Chinese Journal of Applied Chemistry ›› 1992, Vol. 0 ›› Issue (3): 37-40.

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MANGANESE(Ⅲ) COMPLEXES OF SCHIFF BASES DERIVED FROM β-DIKETONE AND β-ALANINE

Chen Ke, Wu Zhiping   

  1. Department of Chemistry, Zhejiang university, Hangzhou 310027
  • Received:1991-04-04 Revised:1991-08-20 Published:1992-06-10 Online:1992-06-10

Abstract: Di and trinuclear manganes(Ⅲ) complexes:Mn2 (Hacala-β)2 (O2CMe)4 and Mn3O(bzalaβ)2(O2CMe)3·4H2O,where Haeala-β- and bzala-β2- are the Schiff base anions prepared by condensing β-alanine with acetylacetone and benzoylaeetone respectively, have been synthesized and studied by electronic conductivity, magnetic susceptibility, thermal analyses, IR and UV-Vis spectra measurements.

Key words: manganese (Ⅲ)complex, Schiff base, β-diketone, β-alanine