Chinese Journal of Applied Chemistry ›› 1992, Vol. 0 ›› Issue (2): 73-75.

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PREPARATION AND SPECTRAL PROPERTIES OF [T(p-NO2)PP]Fe(Ⅱ)(NO) COMPLEX

Shi Tongshun, Liu Bencai, Cao Xizhang   

  1. Department of Chemistry, Jilin University, Changchun 130023
  • Received:1991-02-06 Revised:1991-05-15 Published:1992-04-10 Online:1992-04-10

Abstract: The nitric oxide complex of meso-tetra(p-nitrophenyl) porphinatoiron(Ⅱ)([T(p-NO2)PP] Fe(Ⅱ)(NO)) was prepared.The molecular structure of the complex was examined by means of UV-YIS, IR and EPR. The reaction of [T(p-NO2)PP]Fe(Ⅲ)Cl with NO and the effects of solvents on the absorption spectra of [T(p-NO2)PP]Fe(Ⅱ)(NO) were also studied.

Key words: nitric oxide, porphyrin, spectral property