RADICAL POLYMERIZATION OF DI-ISO-PROPYL FUMARATE

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (5): 10-12.

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RADICAL POLYMERIZATION OF DI-ISO-PROPYL FUMARATE

Song Zhengzhe, Wen Jiumian, Xu Jiping

Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022

Received:1990-05-22 Revised:1990-11-12 Published:1991-10-10 Online:1991-10-10

Abstract

Abstract: Di-iso-propyl fumarate (DiPF) polymerizes easily using azo-bis-isobutyronitrile as aninitiator at 50～80℃.On the basis of IR、¹H NMR and ¹³C NMR spectra measuements, itis concluded that the polymer is formed through vinyl polymerization mechanism.The ove-rall apparent activation energy for polymerization was determined to be 79.8kJ/mol.The glasstransition temperature determined by TBA technique is 203℃.The colorless powder-like polymer is sluble in toluene, benzene, tetrahydrofuran andchloroform.The thermal properties of the polymer are briefly described.

Key words: di-iso-propyl fumarate, radical polymerization

Song Zhengzhe, Wen Jiumian, Xu Jiping. RADICAL POLYMERIZATION OF DI-ISO-PROPYL FUMARATE[J]. Chinese Journal of Applied Chemistry, 1991, 0(5): 10-12.

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RADICAL POLYMERIZATION OF DI-ISO-PROPYL FUMARATE

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