SYNTHESIS AND CHARACTERIZATION OF OXO-BRIDGED TRI-AND TETRANUCLEAR MANGANESE SALICYLIDENE-β-ALANINE COMPLEXES

Chinese Journal of Applied Chemistry ›› 1990, Vol. 0 ›› Issue (3): 24-28.

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SYNTHESIS AND CHARACTERIZATION OF OXO-BRIDGED TRI-AND TETRANUCLEAR MANGANESE SALICYLIDENE-β-ALANINE COMPLEXES

Chen Ke, Song Lulin

Department of Chemistry, Zhejiang University, Hangzhou 310027

Received:1989-07-06 Revised:1989-10-23 Published:1990-06-10 Online:1990-06-10

Abstract

Abstract: Oxo-bridged tri-and Tetranuclear manganese complexes: Mn₃O(salala-β)₃. 3H₂O and Mn₄O₂(salala-β)₃(ClO₄)₂.8H₂O, where salala-β^2-is the dianion of tridentate Shiff base sali-cylidene-β-alanine, have been synthesized and characterized by elemental analyses,valencedetermination, electronic conductivity,magnetic susceptibility, thermogravimetric analyses,infrared and electronic spectra etc. The possible structures of the complexes are suggested.

Key words: manganese, salicylidene-β-alanine, trinuclear complex, tetranuclear complex

Chen Ke, Song Lulin. SYNTHESIS AND CHARACTERIZATION OF OXO-BRIDGED TRI-AND TETRANUCLEAR MANGANESE SALICYLIDENE-β-ALANINE COMPLEXES[J]. Chinese Journal of Applied Chemistry, 1990, 0(3): 24-28.

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SYNTHESIS AND CHARACTERIZATION OF OXO-BRIDGED TRI-AND TETRANUCLEAR MANGANESE SALICYLIDENE-β-ALANINE COMPLEXES

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