Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (5): 56-58.

• Report • Previous Articles     Next Articles

SYNTHESIS OF NITROGENOUS COMPLEXES OF η3-ALLYLIRON IODIDE

Liu Jingzhi, Gao Hongyu, Ma Deqing, Huang Jingqin, Liu Guozhi   

  1. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1988-09-13 Revised:1989-02-15 Published:1989-10-10 Online:1989-10-10

Abstract: In this work usin g ligands exchange reaction between η3-allylirontricarbonyl iodideand α,α′-dipyridyl or phenanthrolire, two new and catalytically active nitrogenous comp-lexes of η3-allyliron halide, η3-C3H5FeI(CO) dipy and η3-C3H5 FeI(CO)phen,were synthesi-zed successfully.Their chemical structures were characterized by elemental analysis, GCand IR.

Key words: Nitrogenous complex of η3-allyliron iodide, η3-Allylirontricarbonyl iodide, Ligands exchange