Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (2): 73-76.

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CRYSTAL STRCTURE OF BIS(1,8-NAPHTHYRIDINE-N-OXIDE)COPPER(Ⅱ)NITRATE

Gan Xinmin1, Tang Ning1, Zhang Wenjun1, Tan Minyu1, Wang Xin2, Zhu Yin2   

  1. Department of Chemistry, Lanzhou University
  • Received:1988-04-22 Revised:1988-08-16 Published:1989-04-10 Online:1989-04-10

Abstract: The crystal and molecular structure of the title compound was determined fromsingle crystal X-ray diffraction. The complex crystallizes in monoclinic space groupP21/n with Z= 2. Lattice parameters are: a = 7.768(2), b= 13.976(2), c= 9.045(3)Å,6 = 113.12(3)?. The structure was solved by the direct method and Fourier techniques andrefined full-matrix least-squares to R = 0.035 for 1579 reflections. The Cu2+ ion is 6-cooordinate, being bonded to two oxygen toms from two unidentate nitrate groups andtwo nitrogen atoms and two oxygen atoms from two organic ligands. Each Cu2+ ion iscoordinated In a distorted octahedral configuration.

Key words: Copper nitrate, 1, 8-Naphthyridine-N-oxide, Complex, Crystal structure