SYNTHESES OF BINUCLEAR COMPLEXES [C5H5Fe(CO)2]-LnCl2·nTHF AND [C5H5Fe(CO)2] [C5H4(SiMe3)] LnCl·nTHF

Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (2): 5-10.

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SYNTHESES OF BINUCLEAR COMPLEXES [C₅H₅Fe(CO)₂]-LnCl₂·nTHF AND [C₅H₅Fe(CO)₂] [C₅H₄(SiMe₃)] LnCl·nTHF

Nie Guojun, Hu Ninghai, Jin Zhongsheng, Chen Wenqi

Changchun Institute of Applied Chemistry, Academia Sinica

Received:1987-11-04 Revised:1988-08-18 Published:1989-04-10 Online:1989-04-10

Abstract

Abstract: In this paper the preparation of the binuclear complexes [C₅H₅Fe(CO)₂]LnCl₂·nTHF(Ln = Nd, Sm, Gd; n = 1,2) and [C₅H₅Fe(CO)₂][C₅H₄ (SiMe₃)]LnCl·nTHF (Ln = Nd, Sm,Gd; n = 0,1,3) is reported. Both complexes were identified by clemental analyses, thermalgravimetric analyses, infrared spectra, mass spectra, NMR and EPR. The infraredspectral data reveal the bridging carbonyls between the iron and the rare earth elements.[C₅H₅Fe(CO)₂]₂Na·4THF as a reaction intermediate in the preparation of [C₅H₅Fe-(CO)₂]LnCl₂ nTHF was characterized by crystal structural analyses.

Key words: Binuclear complex, Cyclopentadienyldicarbonyliron sodium, Trimethylsilylcyclopentadiene, Synthesis

Nie Guojun, Hu Ninghai, Jin Zhongsheng, Chen Wenqi. SYNTHESES OF BINUCLEAR COMPLEXES [C₅H₅Fe(CO)₂]-LnCl₂·nTHF AND [C₅H₅Fe(CO)₂] [C₅H₄(SiMe₃)] LnCl·nTHF[J]. Chinese Journal of Applied Chemistry, 1989, 0(2): 5-10.

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SYNTHESES OF BINUCLEAR COMPLEXES [C₅H₅Fe(CO)₂]-LnCl₂·nTHF AND [C₅H₅Fe(CO)₂] [C₅H₄(SiMe₃)] LnCl·nTHF

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