INFRARED SPECTRA OF CROWN ETHER COMPLEXES OF LUTHIUM SALTS

Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (2): 48-51.

• Full Papers • Previous Articles Next Articles

INFRARED SPECTRA OF CROWN ETHER COMPLEXES OF LUTHIUM SALTS

Zhao Ming, Zhang Qinglian(T. L. Chang)

Department of Chemistry, Peking University

Received:1988-01-23 Revised:1988-05-04 Published:1989-04-10 Online:1989-04-10

Abstract

Abstract: Two new complexes, LiBr·(CH₂CH₂O)₅·H₂O and CF₃COOLi·(CH₂CH₂O)₆·3H₂O, wereprepared and their in frated spectra(400-4000cm^-1)were examined. The infrared study includeda similar (CH₂CH₂O)₅ complex of LiCl, and also similar (CH₂CH₂O)₆ complexes of LiCl,LiBr and LiClO₄, but with 5H₂O, 5H₂O and 2THF·3H₂O respectively. Assignment of thevarious absorption bands was performed. Evidence was found for the splitting of the OHband due to two different modes of dentation(bridge and terminal) of the water molecule,and also for the splitting of the FCF₂ and OCO bands due to the conformational transfor-mation of CF₃COO^- while entering coordination.

Key words: Lithium salt, Crown ether, Complex, Infrared spectrum

Zhao Ming, Zhang Qinglian(T. L. Chang). INFRARED SPECTRA OF CROWN ETHER COMPLEXES OF LUTHIUM SALTS[J]. Chinese Journal of Applied Chemistry, 1989, 0(2): 48-51.

[1]	Li-Yan CHEN, Zi-Ming ZHAO, Jin-Qi TAO, Yu-Zhen ZHANG, Gang CHENG, Yun-Jun SHEN. Synthesis of Mono- and Binuclear Disulfur-Chelated Organoplatinum（Ⅱ） Complexes and Its OLEDs Application [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 236-244.
[2]	Guan-Yu XIE, Mao LI. Topological Metallopolymers Synthesized by Electropolymerization and Their Photoelectric Properties [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1246-1251.
[3]	Jing-Hui WEN, Bing ZHAO, Wei KAN, Li-Yan WANG, Li SUN, Tian-Shu SONG, Bo SONG. Synthesis of Isomers of Distinguishable Iron（Ⅲ） Fluorescent Probes and Application in Water Samples [J]. Chinese Journal of Applied Chemistry, 2022, 39(5): 787-796.
[4]	Hong-Xia CHEN, Bao-Xia LI, Ying-Ming YAO, Peng LIU. Synthesis， Characterization and Catalytic Activity of Benzylamine⁃bridged Bis（phenolato）lanthanide Complexes [J]. Chinese Journal of Applied Chemistry, 2022, 39(5): 843-851.
[5]	Zi-Ang WANG, Li-Xing CAO, Pan SHAO, Meng-Yu ZHU, En-Ning LIU, Shuang LIANG, Yang XING, Ling DI, Zhan-Xu YANG. Detection and Theoretical Study of Fukui Function of Nitroaromatics by Carbazole‑Based Iridium（Ⅲ） Phosphorescent Probe [J]. Chinese Journal of Applied Chemistry, 2022, 39(10): 1617-1626.
[6]	GAO Jia-Xing, CHEN Long, YU Jia-Ting, GUO Xu-Dong, HU Rui, WANG Shuang-Qing, CHEN Jin-Ping, LI Yi, YANG Guo-Qiang. Research Progress on High Resolution Extreme Ultraviolet Photoresist [J]. Chinese Journal of Applied Chemistry, 2021, 38(9): 1138-1153.
[7]	SHE Yun-Ting, YANG Chang-Yu, LI De-Liang, CHANG Zhi-Xian. Reactive Extraction of Amphoteric Organics from the Dilute Solutions [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 24-35.
[8]	YAO Meiren, WANG Kangjun, ZHANG Yajing, WANG Dongping. Application of Sterically Hindered Chiral (Pyrrolidine Salen) Mn(III) Complex in Asymmetric Epoxidation of Alkenes [J]. Chinese Journal of Applied Chemistry, 2020, 37(8): 889-895.
[9]	XIE Xingqin. Interaction Mechanism Between Thiourea Aryl Iridium Anticancer Complex and Bovine Serum Albumin [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 604-610.
[10]	ZENG Huijuan, LIN Meijuan, LIU Chao, CHEN Longjie, ZHANG Yushan, LING Qidan. White Phosphorescent Star-Shape Polymers Derived from Poly(fluorene-carbazole) with Green-Yellow Iridium Complex as the Cores [J]. Chinese Journal of Applied Chemistry, 2020, 37(1): 16-23.
[11]	HEI Jiahui, YANG Lining, LI Jun. Synthesis and Photocatalysis of Metal Complexes with Schiff Base Derived from 2-Thiophene Carboxaldehyde and Ethylenediamine [J]. Chinese Journal of Applied Chemistry, 2019, 36(8): 949-957.
[12]	WANG Jun,LIU Jinyi,CHEN Liduo,LAN Tianyu,WANG Libo. Synthesis and Ethylene Oligomerization Behavior of Hyperbranched Bispyridineimine Chromium Catalyst [J]. Chinese Journal of Applied Chemistry, 2019, 36(7): 773-781.
[13]	WU Dan,WANG Tinglan,WANG Jinglin,YAO Yuan,TANG Songchao. A Durable Hydrophobic Surface Fabricated Through Stereocomplexation and Self-assembly [J]. Chinese Journal of Applied Chemistry, 2019, 36(6): 622-630.
[14]	WU Dan, WANG Tinglan, WANG Jinglin, YAO Yuan, TANG Songchao. A Durable Hydrophobic Surface Fabricated Through Stereocomplexation and Self-assembly [J]. Chinese Journal of Applied Chemistry, 2019, 36(6): 0-0.
[15]	BAO Jinping, FAN Sufang, YANG Guoyu, WANG Zhimin, WANG Ying, LIU Xiaohua, XU Cuilian. Synthesis and Antifungal Activities of Chitosan Oligosaccharide Thiosemicarbazone Schiff Base Cu(Ⅱ) Complex [J]. Chinese Journal of Applied Chemistry, 2019, 36(5): 500-508.

INFRARED SPECTRA OF CROWN ETHER COMPLEXES OF LUTHIUM SALTS

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments