Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (1): 60-62.

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SYNTHESES OF TRIMETHYLSIL YLCYCLOPENTADIENYL LANTHANIDE DICHLORIDES

Nie Guojun, Wang Jingcheng, Chen Wenqi   

  1. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1987-11-04 Revised:1988-04-08 Published:1989-02-10 Online:1989-02-10

Abstract: The trimethylsilylcyelopentadienyl lanthanide dichlorides Cp 'LnCl2·nTHF (Cp' = trime-thylsilylcyclopentadienyl; Ln = Nd, Sm, Gd; n = 0, 1, 2) were synthesized and characterizedby elemental analyses, infrared spectra, nuclear magnetic resonance and thermal gravimetrytechniques.During the synthesis the dimer of trimethylsilylcyclopentadiene was appeared inthe solution.

Key words: Trimethylsilylcyclopentadienyl lanthanide dichloride, Trimethylsilylcyclopentadiene, Lanthanide complexes