A STUDY ON SUPPORTED CO3[Fe(CN6)]2 AND HYDROGENATION OF CN

Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (1): 63-65.

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A STUDY ON SUPPORTED CO₃[Fe(CN₆)]₂ AND HYDROGENATION OF CN

Lu Lude, Wang Xin, Song Qize, Yang Xujie

Department of Chemical Engineering, East China Institute of Technology, Nanjing

Received:1988-01-23 Revised:1988-07-18 Published:1989-02-10 Online:1989-02-10

Abstract

Abstract: This study deals with properties and thermal reactions of Co₃[Fe(CN)₆]₂ supported onsilica, γ-alumina and magnesia. The final solid products of thermal decomposition in hy-drogen atmosphere consisted of Co-Fe alloy and highly dispersed surface Fe(Ⅱ)ions.HCNwas formed on silica and γ-alumina as a result of (CN)₂ hydrogenation. Neither HCN norNH₃ was produced on magnesia because of the basicity of the support. Thus HCN maybe considered as an intermediate of the hydrogenation process from (CN)₂ to NH₃.

Key words: Cobalt ferricyanide, Cyanogen, Catalytic hydrogenation, Thermal reaetion

Lu Lude, Wang Xin, Song Qize, Yang Xujie. A STUDY ON SUPPORTED CO₃[Fe(CN₆)]₂ AND HYDROGENATION OF CN[J]. Chinese Journal of Applied Chemistry, 1989, 0(1): 63-65.

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A STUDY ON SUPPORTED CO₃[Fe(CN₆)]₂ AND HYDROGENATION OF CN

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