STUDY ON THE REACTION OF TRIPYRIDYL π-ALLYLIRON CHLORIDE AND CROTONALDEHYDE

Chinese Journal of Applied Chemistry ›› 1988, Vol. 0 ›› Issue (4): 46-49.

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STUDY ON THE REACTION OF TRIPYRIDYL π-ALLYLIRON CHLORIDE AND CROTONALDEHYDE

Liu Jingzhi, Guo Xiangfeng, Xiao Yanwen, Liu Guozhi

Changchun Institute of Applied Chemistry, Academia Sinica

Received:1987-03-03 Revised:1987-06-10 Published:1988-08-10 Online:1988-08-10

Abstract

Abstract: The self-condensation of crotonaldehyde was studied in the presence of tripyridyl π-allyl iron chloride.The product was confirmed as 6-methyl 1,3-cyclohexadiene-1-carboxaldehyde by Gc-MS, IR and ¹H NMR.It was suggested that the possible mechanism of the reaction might be the initial ligand exchange of crotonaldehyde with tripyridyl π-allyl iron chloride followed by addition and cyclization with another molecule of crotonaldehyde.The selectivity of reaction was increased greatly by orientation effect of ligand in the complex without side reaction.

Key words: Crotohaldehyde, Self-condensation, Tripyridyl, π-allyl, iron, chloride complex

Liu Jingzhi, Guo Xiangfeng, Xiao Yanwen, Liu Guozhi. STUDY ON THE REACTION OF TRIPYRIDYL π-ALLYLIRON CHLORIDE AND CROTONALDEHYDE[J]. Chinese Journal of Applied Chemistry, 1988, 0(4): 46-49.

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STUDY ON THE REACTION OF TRIPYRIDYL π-ALLYLIRON CHLORIDE AND CROTONALDEHYDE

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