Dihydroxylation of Styrene Catalyzed by Molybdenyl Acetylacetonate

doi:10.3724/SP.J.1095.2014.30592

Chinese Journal of Applied Chemistry

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Dihydroxylation of Styrene Catalyzed by Molybdenyl Acetylacetonate

MAO Rongfang, XU Liming, GAO Xi, CHENG Guangbin, YANG Hongwei^*

(School of Chemical Engineering,Nanjing University of Science & Technology,Nanjing 210094,China)

Received:2013-11-25 Revised:2014-01-16 Published:2014-09-03 Online:2014-09-03

Abstract

Abstract: The catalyst molybdenyl acetylacetonate（MoO2(acac)2） was prepared by reaction of ammonium molybdate and acetylacetone. The effects of solvents, temperature, oxidants, co-catalysts and the ratio of substrate on the dihydroxylation of styrene were investigated. Under the optimized condition, conversion, chemoselectivity and isolated yield of dihydroxylation reaction are 85.2%, 70.7% and 53.3%, respectively. The possible catalytic mechanism and improving directions of catalytic reaction were also discussed.

Key words: molybdenyl acetylacetonate, styrene, dihydroxylation, catalytic mechanism, vicinal diol

CLC Number:

O625

MAO Rongfang, XU Liming, GAO Xi, CHENG Guangbin, YANG Hongwei*. Dihydroxylation of Styrene Catalyzed by Molybdenyl Acetylacetonate[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.30592.

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Dihydroxylation of Styrene Catalyzed by Molybdenyl Acetylacetonate

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