Partial Factorial Analysis for the Stability of Water-in-Oil Type Polyethyleneimine Solution-in-Paraffin Emulsion

doi:10.11944/j.issn.1000-0518.2018.10.170349

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (10): 1234-1242.DOI: 10.11944/j.issn.1000-0518.2018.10.170349

• Full Papers • Previous Articles Next Articles

Partial Factorial Analysis for the Stability of Water-in-Oil Type Polyethyleneimine Solution-in-Paraffin Emulsion

HUANG Dengfa,LIU Yanhua,WANG Feng()

School of Chemical and Material Engineering,Jiangnan University,Wuxi,Jiangsu 214122,China

Received:2017-09-22 Accepted:2018-01-04 Published:2018-10-01 Online:2018-10-09
Contact: WANG Feng
Supported by:
Supported by China Scholarship Council(No.201406795023), Postgraduate Research & Practice Innovation Program of Jiangsu Provence(No.SJCX18_0618)

Abstract

Abstract:

Polyethyleneimine(PEI) and its emulsions have been widely used in enzyme immobilization, gene therapy and waste water treatment, etc. In this work, a partial factorial test was employed to study the main factors and the interaction effect between various factors influencing the stability of water-in-oil(W/O) type PEI solution-in-paraffin emulsion. The results show that the amount of emulsifier and the mass fraction of PEI in aqueous phase are the main factors that influence the stability of the emulsion. The most significant factor is the interaction between the mass fraction of PEI in aqueous phase and the volume ratio of water/oil. The optimum conditions of the emulsion are:20% PEI in the aqueous phase, 0.07 g/mL of the emulsifier, 6:4 volume ratio of water/oil, 3 min of homogenization time and 6000 r/min of the homogenization velocity. The emulsion prepared under the optimal conditions has shown no significant changes of emulsification in a week, indicating its excellent stability.

Key words: polyethyleneimine solution-in-paraffin emulsion, stability, partial factors test, factors interaction

HUANG Dengfa,LIU Yanhua,WANG Feng. Partial Factorial Analysis for the Stability of Water-in-Oil Type Polyethyleneimine Solution-in-Paraffin Emulsion[J]. Chinese Journal of Applied Chemistry, 2018, 35(10): 1234-1242.

References

[1]	Jung H,Kim S A,Lee E,et al. Linear Polyethyleneimine-Doxorubicin Conjugate for pH-Responsive Synchronous Delivery of Drug and MicroRNA-34a[J]. Macromol Res,2015,23(5):449-456.
[2]	WANG Dongmei,CAO Jinli,ZHANG Yi,et al. The Structure Characterization of Polyethylenimine via FTIR[J]. Spectrosc Spectr Anal,2016,(S1):199-200(in Chinese). 王冬梅,曹金丽,张怡,等. 红外光谱法研究聚乙烯亚胺的结构[J]. 光谱学与光谱分析,2016,(S1):199-200.
[3]	Guo X,Ding L,Kanamori K,et al. Functionalization of Hierarchically Porous Silica Monoliths with Polyethyleneimine(PEI) for CO 2 Adsorption[J]. Micropor Mesopor Mater,2017,245:51-57.
[4]	Bayramoglu G,Arica M Y. Adsorption of Cr(Ⅵ) onto PEI Immobilized Acrylate-based Magnetic Beads:Isotherms, Kinetics and Thermodynamics Study[J]. Chem Eng J,2008,139(1):20-28.
[5]	Sahiner N,Demirci S,Sahiner M,et al. The Synthesis of Desired Functional Groups on PEI Microgel Particles for Biomedical and Environmental Applications[J]. Appl Surf Sci,2015,354:380-387.
[6]	Zhang X Q,Intra J,Salem A K.Comparative Study of Poly(lactic-co-glycolic acid)-Poly Ethyleneimine-Plasmid DNA Microparticles Prepared Using Double Emulsion Methods[J]. J Microencapsul,2008,25(1):1-12.
[7]	LIU Pei,NIE Tingting,WANG Feng.Preparation of Polyamine Microsphere and Its Protein Adsorption Properties[J]. Chem Ind Eng Prog,2013,32(2):404-409(in Chinese). 刘培,聂婷婷,王峰. 新型聚胺基微球制备及其吸附蛋白质性质[J]. 化工进展,2013,32(2): 404-409.
[8]	Chiang C L,Sung C S.Purification of Transfection-grade Plasmid DNA from Bacterial Cells with Superparamagnetic Nanoparticles[J]. J Magn Magn Mater,2006,302(1):7-13.
[9]	Rodriguez M,Lapierre J,Ojha C R,et al. Intranasal Drug Delivery of Small Interfering RNA Targeting Beclin1 Encapsulated with Polyethylenimine(PEI) in Mouse Brain to Achieve HIV Attenuation[J]. Sci Rep,2017,7(1):1862.
[10]	Matos M,García C F,Suárez M A,et al. Treatment of Oil-in-Water Emulsions by a Destabilization/Ultrafiltration Hybrid Process:Statistical Analysis of Operating Parameters[J]. J Taiwan Inst Chem Eng,2016,59:295-302.
[11]	ZHOU Yonghua,YE Hongqi,ZHONG Hong.Chemical Demulsification and Immobilization of Pd Nanoparticles in W/O Microemulsion by Conductivity Method[J]. Chinese J Process Eng,2008,8(6):1163-1166(in Chinese). 周永华,叶红齐,钟宏. 电导率法研究W/O微乳液中Pd纳米微粒的化学破乳负载[J]. 过程工程学报,2008,8(6):1163-1166.
[12]	ZHANG Wen,TAO Senlin,SU Hongying,et al. Latent Heat of Melting of Mg-based Eutectic Alloys as High Temperature Phase Change Materials for Latent Heat Storage[J]. J Funct Mater,2017,48(2):2231-2235(in Chinese). 张稳,陶森林,苏红莹,等. 葡聚糖水凝胶微球的制备与表征[J]. 功能材料,2017,48(2):2231-2235.
[13]	FANG Hongbo,LIN Yun,LIN Meiqin,et al. Effects of Acrylamide Polymer and Foamer on Oil-water Interfacial Properties and Emulsion Stability[J]. China Surfactant Deterg Cosmet,2010,40(4):235-241(in Chinese). 方洪波,林云,林梅钦,等. 丙烯酰胺聚合物与发泡剂对油水界面性质及乳状液稳定性的影响[J]. 日用化学工程,2010,40(4):235-241.
[14]	KANG Wanli,LI Jinhuan,ZHAO Xueqian.Effects of Interfacial Tension and Millet Size on Emulsion Stability[J]. Oil-Gasfield Surf Eng,2005,24(1):11-12(in Chinese). 康万利,李金环,赵学乾. 界面张力和乳滴大小对乳状液稳定性的影响[J]. 油气田地面工程,2005,24(1):11-12.
[15]	CUI Zhenggang. Fundamentals of Surfactants, Colloids, and Interface Chemistry[M]. Beijing:Chemical Industry Press,2013:238-240(in Chinese). 崔正刚. 表面活性剂,胶体与界面化学基础[M]. 北京:化学工业出版社,2013:238-240.

Partial Factorial Analysis for the Stability of Water-in-Oil Type Polyethyleneimine Solution-in-Paraffin Emulsion

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Ting WANG, Qi WEI, Qiang FU, Wei LI, Shi-Wei WANG. Review of Perovskite Photovoltaic Cell Encapsulation Material and Technology [J]. Chinese Journal of Applied Chemistry, 2022, 39(9): 1321-1344.
[2]	Chen-Si-Fan JIAO, Shao‑Bo ZHENG, Peng-Jun XU, Wei WANG, Takebe HIROMICHI, Mukai KUSUHIRO, Zhong-Da YU. Method of Evaluating the Foaming Properties of Surfactant Solutions— Real Sphere Bubble Method [J]. Chinese Journal of Applied Chemistry, 2022, 39(7): 1108-1118.
[3]	Xin-Wei DU, Wen-Jie ZHAO, Wei HU, Zhao-Yan SUN, Wan-Li LIU, Tian-Lei REN, Ming-Xing FU. Preparation and Properties of Poly（ether ether ketone）/Carbon Nanotube Modified Polypropylene Janus Composite Separator [J]. Chinese Journal of Applied Chemistry, 2022, 39(12): 1862-1869.
[4]	He LI, Gong LI, Xue GONG, Ming-Bo RUAN, Ce HAN, Ping SONG, Wei-Lin XU. Research on Performance Decay Mechanism of Pt/C Catalyst in Long‑Term ORR Test [J]. Chinese Journal of Applied Chemistry, 2022, 39(10): 1564-1571.
[5]	ZHAO Chang-Li, QIN Ming-Gao, DOU Xiao-Qiu, FENG Chuan-Liang. High Mechanical Stability and Osteogenesis of Chiral Supramolecular Hydrogel Induced by Inorganic Nanoparticles [J]. Chinese Journal of Applied Chemistry, 2022, 39(1): 177-187.
[6]	Ying ZHAO, Yi-Jia SHAO, Luo-Qian LI, Jian-Wei REN, Shi-Jun LIAO. Research Progress on the Degradation Mechanism and Cycle Stability Improvement of Lithium-Rich Cathode Materials [J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 205-222.
[7]	QIAO Zong-Wen, CHEN Tao. Properties of Pyrenesulfonic Type Sulfonated Polysulfone Cation Exchange Membrane with High Performance Long Side Chain [J]. Chinese Journal of Applied Chemistry, 2021, 38(6): 668-674.
[8]	WU Zhen-Jiang, HUO Xiao-Wei, LIU Shou-Jun, YANG Song. Preparation and Application of Resin-Free Color Pastes in Water-Based Pigment Systems [J]. Chinese Journal of Applied Chemistry, 2021, 38(2): 212-219.
[9]	CAO You-Peng, PANG Xuan, XIANG Sheng, WANG Tian-Chang, FENG Li-Dong, BIAN Xin-Chao, LI Gao, CHEN Xue-Si. Solution-Induced Co-crystallization in Poly(lactic acid)/ Substituted Poly(lactic acid) Blends [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 60-68.
[10]	QIAO Zongwen, ZHAO Benbo. Properties of Sulfonated Polysulfone Proton Exchange Membranes Based on One-Pot Method [J]. Chinese Journal of Applied Chemistry, 2020, 37(6): 658-665.
[11]	AN Lulu, MI Jie. Synthesis of Nickel Cobalt Hydroxide and Its Electrochemical Properties [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 579-586.
[12]	WEN Pushan, HE Rui, ZHAO Guanglian, LIANG Xing, LEE Myonghoon. Preparation and Properties of Soluble Polyimides as the Liquid Crystal Alignment Layer [J]. Chinese Journal of Applied Chemistry, 2020, 37(12): 0-0.
[13]	WEN Pushan, HE Rui, ZHAO Guanglian, LIANG Xing, LEE Myonghoon. Preparation and Properties of Soluble Polyimides as the Liquid Crystal Alignment Layer [J]. Chinese Journal of Applied Chemistry, 2020, 37(12): 1403-1410.
[14]	FU Fengyan, CHENG Jingquan, ZHANG Jie, GAO Zhihua. Recent Development in Ionic Exchange Groups-Based Anion Exchange Membrane [J]. Chinese Journal of Applied Chemistry, 2020, 37(10): 1112-1126.
[15]	WANG Zhumei,LI Yueming,WAN Detian,ZUO Jianlin,SHEN Zongyang,LI Kai. Preparation and Stability of Silica Coated Bismuth-Based Yellow Pigments [J]. Chinese Journal of Applied Chemistry, 2020, 37(1): 109-116.