Determination of Hydrogen Sulfide in Water by Biphenyl Ratio Fluorescence Probe

doi:10.11944/j.issn.1000-0518.2017.04.160301

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (4): 449-455.DOI: 10.11944/j.issn.1000-0518.2017.04.160301

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Determination of Hydrogen Sulfide in Water by Biphenyl Ratio Fluorescence Probe

WANG Ning,ZHOU Dongxue,YANG Jinchuang,AN Yue(),LYU Chengwei()

College of Chemistry and Chemical Engineering,Liaoning Normal University,Dalian,Liaoning 116029,China

Received:2016-07-28 Accepted:2016-11-09 Published:2017-03-31 Online:2017-03-31
Contact: AN Yue,LYU Chengwei
Supported by:
Supported by the National Natural Science Foundation of China(No.21403100), the Higher Education Research Program of Education Department of Liaoning Province of China(No.L2014421)

Abstract

Abstract:

A biphenyl-derived ratiometric fluorescent probe(WN) for the detection of H₂S was synthesized using 4,4'-biphenyl dicarboxylic acid as the raw material and characterized by ¹H NMR, ¹³C NMR, and MS. For the purpose of detection of H₂S in aqueous solution, its fluorescent properties had been systematically researched. The results show that probe WN exhibits good sensitivity and selectivity for detection of H₂S, response time is 12 min. WN has strong anti-interference ability to biological mercaptan(Cys, Gsh), active oxides(H₂O₂, ClO^-), various anions and cations(H₂PO4-, SO42-, Cl^-, HCO3-, CO32-, Mg²⁺, Zn²⁺, K⁺, Ca²⁺, Na⁺), and a good fluorescence response in a wide pH range, the fluorescence in tensity has good linear relation ships with H₂S in the range of 1.1~350 μmol/L(R²=0.9943), the detection limit of H₂S is estimated to be 1.07×10^-6 mol/L. The test for three different water samples shows that the probe WN has a certain application significance in the detection of H₂S in water.

Key words: hydrogen sulfide, azide group, ratiometric fluorescent probe

WANG Ning, ZHOU Dongxue, YANG Jinchuang, AN Yue, LYU Chengwei. Determination of Hydrogen Sulfide in Water by Biphenyl Ratio Fluorescence Probe[J]. Chinese Journal of Applied Chemistry, 2017, 34(4): 449-455.

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Determination of Hydrogen Sulfide in Water by Biphenyl Ratio Fluorescence Probe

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