Synthesis, Structure and Fluorescence Properties of Manganese(Ⅱ) Complex Based on 3-Carboxyl-1,2,4-triazole

doi:10.11944/j.issn.1000-0518.2017.03.160210

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (3): 354-360.DOI: 10.11944/j.issn.1000-0518.2017.03.160210

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Synthesis, Structure and Fluorescence Properties of Manganese(Ⅱ) Complex Based on 3-Carboxyl-1,2,4-triazole

TAN Yuhui,GU Zhifeng,LIU Yi,YANG Changshan,WANG Bin,TANG Yunzhi()

School of Materials and Chemical Engineering,Jiangxi University of Science and Technology,Ganzhou,Jiangxi 341000,China

Received:2016-05-20 Accepted:2016-09-28 Published:2017-02-27 Online:2017-02-27
Contact: TANG Yunzhi
Supported by:
Supported by the National Natural Science Foundation of China (No. 21261009, No. 21461010, No. 21471070) and the Science and Technology Support Program of Jiangxi Provincial Science and Technology Department

Abstract

Abstract:

In order to investigate the properties of 3-carboxyl-1,2,4-triazole complexes, a novel complex, [Mn(C₃H₂N₃O₂)₂(H₂O)₂], was synthesized by the hydrothermal method. The properties of the complex were characterized by Fourier transform infrared spectroscopy(IR), element analysis, thermal gravimetric anlysis(TGA) and powder X-ray diffraction(PXRD). The single crystal X-ray analysis reveals that the complex is a unique single-core structure and belongs to the monoclinic crystal system in space group P21/c. The coordination number of Mn^Ⅱ is six. The Mn^Ⅱ atom is located on an inversion centre. Each Mn^Ⅱ atom is coordinated by two O atoms and two N atoms from two 3-carboxyl-1,2,4-triazole anions and two coordinated water molecules to form a slightly distorted octahedral geometry. The discrete molecules of the complex are furthermore linked, resulting in a three-dimensional network structure through extensive intermolecular hydrogen bonds and π-π interactions. Solid fluorescence of the complex shows an emission peak at 517 nm. Compared with the ligand, there is a 7 nm blue shift. The research provides a reference for exploiting new metal-organic complex fluorescent materials.

Key words: hydrothermal method, carboxyl-triazole, fluorescence properties

TAN Yuhui, GU Zhifeng, LIU Yi, YANG Changshan, WANG Bin, TANG Yunzhi. Synthesis, Structure and Fluorescence Properties of Manganese(Ⅱ) Complex Based on 3-Carboxyl-1,2,4-triazole[J]. Chinese Journal of Applied Chemistry, 2017, 34(3): 354-360.

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Synthesis, Structure and Fluorescence Properties of Manganese(Ⅱ) Complex Based on 3-Carboxyl-1,2,4-triazole

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