Simultaneous Adsorption of Copper Ion(Ⅱ) and Biphenol A onto Citrate-modified Layered Double Hydroxides with Dodecylbenzenesulfonate

doi:10.11944/j.issn.1000-0518.2015.07.140444

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (7): 816-824.DOI: 10.11944/j.issn.1000-0518.2015.07.140444

• Full Papers • Previous Articles Next Articles

Simultaneous Adsorption of Copper Ion(Ⅱ) and Biphenol A onto Citrate-modified Layered Double Hydroxides with Dodecylbenzenesulfonate

LI Yan^*, WANG Guowang, WANG Ning

Department of Chemistry,Changzhi College,Changzhi,Shanxi 046011,China

Received:2014-12-25 Accepted:2015-03-27 Published:2015-06-30 Online:2015-06-30
Contact: Yan LI
Supported by:
Project supported by the Natural Science Foundation of Shanxi Province(No.2013011040-8), National Training Programs of Innovation and Entrepreneurship for Undergraduates(No.201310122002), Training Programs of Innovation and Entrepreneurship for Undergraduates in Shanxi Province(No.2014431), Teaching Reform Project of Colleges and Universities in Shanxi Province(No.J2013104), the Twelfth Five Year Plan Project of Education Science in Shanxi Province(No.GH-12086)

Abstract

Abstract:

A novel type of adsorptive material, dodecylbenzenesulfonate(DBS)-citrate(Cit)-layered double hydroxide (LDHs), DBS-Cit-LDHs, was synthesized by modifying Mg-Al LDHs with both DBS^- and citrate^3- anions using ion-exchange method. DBS-Cit-LDHs was characterized by powder X-ray diffraction, Fourier transform infrared spectroscopy, low-temperature N₂ adsorption, and elemental analysis. The surface property and structure of DBS-Cit-LDHs are significantly altered from Mg-Al LDHs. Batch adsorption experiments indicate that DBS-Cit-LDHs can simultaneously adsorb biphenol A(BPA) and Cu²⁺ from the mixed solution. The adsorption kinetics of Cu²⁺ and BPA can be well fitted with the pseudo-second order kinetic model and pseudo-first order kinetic model, respectively. The adsorption isotherm of Cu²⁺ and BPA can be well fitted with the Freundlich and Linear equations, respectively. BPA adsorption is attributed to a partition retention mechanism. Cu²⁺ adsorption is dominated by the formation of complexes between Cu²⁺ and citrate^3- anions in the interlayer of DBS-Cit-LDHs. The negative values of ΔG^o and ΔH^o observed for BPA and Cu²⁺ adsorption confirm the spontaneity and exothermic nature, respectively. These results indicate the potential application of DBS-Cit-LDHs in treating wastewater containing both organic compounds and heavy metals.

Key words: layered double hydroxides, dodecylbenzenesulfonate, citrate, simultaneous adsorption, copper ion(Ⅱ), biphenol A

CLC Number:

LI Yan, WANG Guowang, WANG Ning. Simultaneous Adsorption of Copper Ion(Ⅱ) and Biphenol A onto Citrate-modified Layered Double Hydroxides with Dodecylbenzenesulfonate[J]. Chinese Journal of Applied Chemistry, 2015, 32(7): 816-824.

References

[1]	Fu F,Wang Q. Removal of Heavy Metal Ions from Wastewaters:A Review[J]. J Environ Manage,2011,92(3):407-418.
[2]	Soto M L,Moure A,Domínguez H,et al.Recovery, Concentration and Purification of Phenolic Compounds by Adsorption:A Review[J]. J Food Eng,2011,105(1):1-27.
[3]	XIA Yan,ZHU Runliang,TAO Qi,et al.Sorption of Nitrobenzene to Anionic Surfactant Modified Layered Double Hydroxides[J]. Environ Sci,2013,34(1):226-230(in Chinese). 夏燕,朱润良,陶奇,等. 阴离子表面活性剂改性水滑石吸附硝基苯的特性研究[J]. 环境科学,2013,34(1):226-230.
[4]	LI Yan,SHI Liwen,LIU Zhishan,et al.Sorption of o-Cresol on Pristine, Calcined and Modified Hydrotalcite-Like Compounds[J]. Acta Chim Sin,2012,70(6):683-690(in Chinese). 李燕,施利文,刘志山,等. 邻甲酚在类水滑石、焙烧及改性类水滑石上的吸附[J]. 化学学报,2012,70(6):683-690.
[5]	Gherasim C V,Mikulášek P. Influence of Operating Variables on the Removal of Heavy Metal Ions from Aqueous Solutions by Nanofiltration[J]. Desalination,2014,343(1):67-74.
[6]	Qu X,Tian M,Liao B,et al.Enhanced Electrochemical Treatment of Phenolic Pollutants by an Effective Adsorption and Release Process[J]. Electrochim Acta,2010,55(19):5367-5374.
[7]	Lu Y,Wu Z,Li M,et al.Hydrophilic PVA-co-PE Nanofiber Membrane Functionalized with Iminodiacetic Acid by Solid-phase Synthesis for Heavy Metal Ions Removal[J]. React Funct Polym,2014,82(1):98-102.
[8]	Du L C,Qu B J. Structural Characterization and Thermal Oxidation Properties of LLDPE/MgAl-LDH Nanocomposites[J]. J Mater Chem,2006,16(16):1549-1554.
[9]	Hu G,Wang N,O'Hare, D,et al. Synthesis of Magnesium Aluminum Layered Double Hydroxides in Reverse Microemulsions[J]. J Mater Chem,2007,17(21):2257-2266.
[10]	Pavlovic I,Pérez M R,Barriga C.et al.Adsorption of Cu2+, Cd2+ and Pb2+ Ions by Layered Double Hydroxides Intercalated with the Chelating Agents Diethylenetriaminepentaacetate and Meso-2,3-dimercaptosuccinate[J]. Appl Clay Sci,2009,43(1):125-129.
[11]	Pérez M R,Pavlovic I,Barriga C,et al.Uptake of Cu2+, Cd2+ and Pb2+ on Zn-Al Layered Double Hydroxide Intercalated with Edta[J]. Appl Clay Sci,2006,32(3/4):245-251.
[12]	Kameda T,Takeuchi H,Yoshioka T. Uptake of Heavy Metal Ions from Aqueous Solution Using Mg-Al Layered Double Hydroxides Intercalated with Citrate, Malate, and Tartrate[J]. Sep Purif Technol,2008,62(2):330-336.
[13]	You Y,Zhao H,Vance G F. Surfactant-Enhanced Adsorption of Organic Compounds by Layered Double Hydroxides[J]. Colloids Surf A,2002,205(3):161-172.
[14]	Klumppa E,Contreras O C,Klahre P,et al.Sorption of 2,4-Dichlorophenol on Modified Hydrotalcites[J]. Colloids Surf A,2003,230(1/2/3):111-116.
[15]	Kameda T,Saito M,Umetsu Y. Preparation of a Composite Material for the Uptake of Bisphenol A from Aqueous Solutions, the Dodecylsulfate Ion-Intercalated Mg-Al Layer-Structured Double Hydroxide Particles[J]. J Alloy Compd,2005,402(1/2):46-52.
[16]	Qiu D P,Hou W G. Synthesis and Characterization of Indole-3-butyric Acid/Hydrotalcite-Like Compound Nanohybrids[J]. Colloids Surf A,2009,336(1/2/3):12-17.
[17]	Ulibarri M A,Pavlovic I,Barriga C,et al.Adsorption of Anionic Species on Hydrotalcite Like Compounds:Effect of Interlayer Anion and Crystallinity[J]. Appl Clay Sci,2001,18(1/2):17-27.
[18]	ZHANG Jie,LI Dianqing,REN Lingling,et al.Assembly of Citrate-Pillared LDHs with Supramolecular Structure[J]. Chinese J Inorg Chem,2004,20(10):1208-1212(in Chinese). 张杰,李殿卿,任玲玲,等. 新原料路线共沉淀法组装超分子结构柠檬酸根插层水滑石[J]. 无机化学学报,2004,20(10):1208-1212.
[19]	LI Yan,ZANG Yunbo,LI Longlong. Adsorption Behavior in Dual-Solutes of Cu(Ⅱ) and p-Cresol by Organo-HTlc Nanohybrids[J]. Environ Chem,2013,32(12):2290-2296(in Chinese). 李燕,臧运波,李龙龙. 有机-类水滑石对Cu(Ⅱ)和对甲酚复合污染的吸附[J]. 环境化学,2013,32(12):2290-2296.
[20]	Yavuz O,Altunkaynak Y,Guzel F. Removal of Copper, Nickel, Cobalt and Manganese from Aqueous Solution by Kaolinite[J]. Water Res,2003,37(4):948-952.
[21]	Li Y H,Ding J,Luan Z,et al.Competitive Adsorption of Pb2+, Cu2+ and Cd2+ Ions from Aqueous Solutions by Multiwalled Carbon Nanotubes[J]. Carbon,2003,41(14):2787-2792.
[22]	Li Y,Bi H Y,Shen S L. Removal of Bisphenol A from Aqueous Solution by a Dodecylsulfate Ion-Intercalated Hydrotalcite-Like Compound[J]. Environ Technol,2012,33(12):1367-1373.
[23]	Gao Z,Du B,Zhang G,et al.Adsorption of Pentachlorophenol from Aqueous Solution on Dodecylbenzenesulfonate Modified Nickel-Titanium Layered Double Hydroxide Nanocomposites[J]. Ind Eng Chem Res,2011,50(9):5334-5345.

Simultaneous Adsorption of Copper Ion(Ⅱ) and Biphenol A onto Citrate-modified Layered Double Hydroxides with Dodecylbenzenesulfonate

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	MA Pingchuan, MA Lili, YANG Zhenghui, GUO Haiquan, GAO Lianxun. Improved Corona-Resistance Properties of Alumina/Polyimide Films with Exfoliated Layered Double Hydroxide Nanosheets [J]. Chinese Journal of Applied Chemistry, 2020, 37(6): 666-672.
[2]	LONG Xia,WANG Yaqiong,JU Min,WANG Zheng,YANG Shihe. Elaboration and Application of Transition Metals Based Layered Double Hydroxides for Electrochemical Water Oxidation [J]. Chinese Journal of Applied Chemistry, 2018, 35(8): 881-889.
[3]	Lei YANG, Yunxing ZHANG, Xiaoqin WANG. Preparation and Release Behavior of Ibuprofen Intercalated Hydrotalcite/Starch Gel Composites [J]. Chinese Journal of Applied Chemistry, 2018, 35(7): 781-787.
[4]	DUAN Yuanshou, JIA Fengxia, WANG Shuo, LI Lifang. Synthesis and Thermosensitivity of Poly(N-isopropylacrylamide)/Hydrotalite Hydrogel [J]. Chinese Journal of Applied Chemistry, 2018, 35(1): 102-108.
[5]	JIAO Yuan, LIU Fuyong, WANG Songbai, SHUANG Shaomin, DONG Chuan. Synthesis of Magnetic Nanocomposites and Sensitive Detection for Copper(Ⅱ) [J]. Chinese Journal of Applied Chemistry, 2017, 34(1): 111-117.
[6]	XIE Fazhi, WANG Xuechun, YANG Peipei, LI Haibin, SHENG Dandan, HU Tingting, XIE Zhiyong. Pure Ca-Al- Layered Double Hydroxides as an Efficient Sorbent for Phosphate [J]. Chinese Journal of Applied Chemistry, 2016, 33(4): 473-480.
[7]	GAO Yanfang, WANG Haishui. Control of Crystalline Polymorphs and Morphologies for Calcium Carbonate with Sodium Citrate [J]. Chinese Journal of Applied Chemistry, 2015, 32(7): 831-836.
[8]	JIN Xiaoqing, CAO Jie, HU Zhongshan, FENG Xiaojuan, HAN Yuqi. Synthesis and Supercapacitor Properties of Graphene/Co-Ni Layered Double Hydroxides Composites [J]. Chinese Journal of Applied Chemistry, 2015, 32(5): 583-590.
[9]	QI Fenglin, ZHANG Xiaoqing, LI Shuping*. Preparation of Layered Double Hydroxides with Regularly Hexagonal Morphology [J]. Chinese Journal of Applied Chemistry, 2013, 30(07): 801-807.
[10]	CHEN Yongmei1*, ZHU Junli2, YU Zhanglong1, WAN Pingyu1. Orthogonal Optimized Synthesis of Dawsonite from Aluminum Citrate [J]. Chinese Journal of Applied Chemistry, 2012, 29(01): 84-89.
[11]	BAI Yanxia1*,2, ZHAO Maiqun2, JIN Wenfeng2, ZHAO Yang2, WANG Yahui2. Influence of Surface Modifications on Dispersion Stability of Zinc Powder [J]. Chinese Journal of Applied Chemistry, 2011, 28(12): 1462-1464.
[12]	WANG Ang-Ran, BAO Yong-Zhong*, WENG Zhi-Xue, HUANG Zhi-Ming. Dispersive Behaviors of Organic Anion Intercalated Layered Double Hydroxides in Organic Solvents [J]. Chinese Journal of Applied Chemistry, 2010, 27(09): 1050-1054.
[13]	CEN Fang-Fang, SHA ZhaoLin, LU Tian-Hong, LI Shu-Ping*. Study on Preparation of Glutamic Acid/ZnAl Layered Double Hydroxides Using Ion Exchange method [J]. Chinese Journal of Applied Chemistry, 2010, 27(05): 553-557.
[14]	CAO Yong1,2, ZHAO Yu1, JIAO Qing-Ze1*. Growth of carbon nanotubes using layered double hydroxides containing iron, cobalt or nickel as catalytic precursors [J]. Chinese Journal of Applied Chemistry, 2010, 27(04): 445-448.
[15]	Fang Jingli. STUDY ON ELECTROLESS Ni-B ALLOY PLATING FROM CITRATE-AMMONIA SYSTEM [J]. Chinese Journal of Applied Chemistry, 1988, 0(6): 44-48.