Preparation and Performance of Chitosan Grafted Polyvinyl Pyrrolidone Film with Iodine

doi:10.11944/j.issn.1000-0518.2015.05.140307

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (5): 498-503.DOI: 10.11944/j.issn.1000-0518.2015.05.140307

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Preparation and Performance of Chitosan Grafted Polyvinyl Pyrrolidone Film with Iodine

GUO Rui, SAI Mingze, ZHANG Min, ZHONG Shiliang, MA Wentao, CHEN Lei, DING Derun^*

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China

Received:2014-09-03 Revised:2014-11-14 Accepted:2014-12-17 Published:2015-05-05 Online:2015-05-05
Contact: DING Derun
Supported by:
Supported by National Natural Science Foundation of China(No.21305086), the National Undergraduate Innovative Training Program(No.201310856012)

Abstract

Abstract:

The CTS-PVP film with iodine was prepared by chitosan(CTS) grafted polyvinyl pyrrolidone(PVP) in the protection of N₂ with dimethyl 2, 2'-azobis(2-methylpropionate)(AIBME) as initiator followed by addition of a certain amounts of iodine in ethanol solution and a gelatin solution. The properties of the film were characterized by infrared(IR), scan electron microscopy(SEM), UV-visible spectroscopy(UV-Vis), differential scanning calorimetry(DSC), etc. The UV-Vis spectrum shows a strong absorption between 200~600 nm for the CTS-PVP film with iodine. The glass transition temperature at 319 ℃ indicates a good thermal stability. The antimicrobial test result shows that the inhibition zone diameters increase along with the increasing amounts of CTS-PVP-I₂ complex liquid. The inhibition zone diameters against Staphylococcus aureus and Escherichia coli are in the range of 16~36 mm, when the added volume of CTS-PVP-I₂ complex fluid is 10 mL or more, implying its high sensitivity and good antibacterial properties.

Key words: chitosan, iodine, film, antibacterial properties, functional materials

CLC Number:

GUO Rui, SAI Mingze, ZHANG Min, ZHONG Shiliang, MA Wentao, CHEN Lei, DING Derun. Preparation and Performance of Chitosan Grafted Polyvinyl Pyrrolidone Film with Iodine[J]. Chinese Journal of Applied Chemistry, 2015, 32(5): 498-503.

References

[1]	Morimoto M, Saimoto H, Usui H, et al.Biological Activities of Carbohydrate-Branched Chitosan Derivatives[J]. Biomacromolecules, 2001, 2(4):1133-1136.
[2]	He Q R, Zhang T Y, Yang Y M, et al.In Vitro Biocompatibility of Chitosan-Based Materials to Primary Culture of Hippocampal Neurons[J]. J Mater Sci, 2009, 20:1457-1466.
[3]	Nair L S, Starnes T, Ko J W, et al.Development of Injectable Thermogelling Chitosan-Inorganic Phosphate Solutions for Biomedical Applications[J]. Biomacromolecules, 2007, 8(12):3779-3785.
[4]	Jana S, Florczyk S J, Leung M, et al.High-Strength Pristine Porous Chitosan Scaffolds for Tissue Engineering[J]. J Mater Chem, 2012, 22:6291-6299.
[5]	Park J S, Choi S H, Moon I S, et al.Eight-Week Histological Analysis on the Effect of Chitosan on Surgically Created One-Wall Intrabony Defects in Beagle Dogs[J]. J Clin Periodontol, 2003, 30(5):443-453.
[6]	CHEN Shilan, LIU Mingzhu, LYU Shaoyu, et al.Preparation and Drug Release Behavior of Chitosan Grafted Poly(methacrylic acid) Gel Bead[J]. Chinese J Appl Chem, 2013, 30(3):252-259(in Chinese). 陈世兰, 柳明珠, 吕少瑜, 等. 壳聚糖-g-聚甲基丙烯酸凝胶粒的制备及其药物释放行为[J]. 应用化学, 2013, 30(3):252-259.
[7]	FENG Xiaoqiang, LI Xiaofang, YANG Sheng, et al.Preparation, Antibacterial Activities of Thiourea-Chitosan-Co(Ⅱ) Complex and Interaction with Bovine Serum Albumin[J]. Chinese J Appl Chem, 2011, 28(9):1012-1016(in Chinese). 冯小强, 李小芳, 杨声, 等. 硫脲壳聚糖Co(Ⅱ)配合物的制备、抑菌活性及与血清白蛋白的作用[J]. 应用化学, 2011, 28(9):1012-1016.
[8]	Sai M Z, Zhong S L, Tang Y, et al.Research on the Preparation and Antibacterial Properties of 2-N-Thiosemicarbazide -6-O-Hydroxypropyl Chitosan Membranes with Iodine[J]. J Appl Polym Sci, 2014, 131, DOI:
[9]	Lavorgna M, Attianese I, Buonocore G G, et al.MMT-Supported Ag Nanoparticles for Chitosan Nanocomposites: Structural Properties and Antibacterial Activity[J]. Carbohydr Polym, 2014, 102:385-392.
[10]	Wang X H, Du Y M, Liu H. Preparation, Characterization and Antimicrobial Activity of Chitosan-Zn Complex[J]. Carbohydr, Polym, 2004, 56(1):21-26.
[11]	Laudenslager M J, Schiffman J D, Schauer C L. Carboxymethyl Chitosan as a Matrix Material for Platinum, Gold, and Silver Nanoparticles[J]. Biomacromolecules, 2008, 9(10):2682-2685.
[12]	Chen S G, Guo Y J, Chen S J, et al.Preparation and Synergistic Antibacterial Effect of Three-Component Cu/TiO2/CS Nanoparticles[J]. J Mater Chem, 2012, 22, 9092-9099.
[13]	Perelshtein I, Ruderman E, Perkas N, et al.Chitosan and Chitosan-ZnO-Based Complex Nanoparticles: Formation, Characterization and Antibacterial Activity[J]. J Mater Chem B, 2013, 1:1968-1976.
[14]	Zwick M M. Poly(vinyl alcohol)-Iodine Complexes[J]. J Appl Polym Sci, 1965, 9(7):2393-2424.
[15]	Xu W J, Zhang W S, Li W, et al.Synthesis of Poly(vinyl acetate) by Degenerative Transfer Polymerization in the Presence of Iodine[J]. J Appl Polym Sci, 2012, 126(1):104-109.
[16]	Shigeno Y, Kondo K, Takemoto K. Functional Monomers and Polymers, 74.Physico-Chemical Study on the Chitosan-Iodine Complexes[J]. Die Angew Makromol Chem, 1980, 91(1):55-67.
[17]	Shigeno Y, Kondo K, Takemoto K. Functional Monomers and Polymers, 91.On the Adsorption of Iodine and Bromine onto Polystyrene-Grafted Chitosan[J]. Die Angew Makromol Chem, 1981, 182(2):709-712.
[18]	Shigeno Y, Kondo K, Takemoto K. Functional Monomers and Polymers.LXX.On the Adsorption of Iodine onto Chitosan[J]. J Appl Polym Sci, 1980, 25(5):731-738.
[19]	TANG Yang, GUO Rui, SAI Mingze, et al.Complex Properties of Low Molecular Weight Quaternay Ammonium Salt of Chitosan with Iodlne[J]. J. Shanghai Univ Engn Sci, 2013, 3:233-238(in Chinese). 唐阳, 郭瑞, 赛明泽, 等. 低相对分子质量壳聚糖季铵盐碘络合物性质[J]. 上海工程技术大学学报, 2013, 3:233-238.
[20]	Wang L N, Liu F, Jiang Y F, et al.Synergistic Antimicrobial Activities of Natural Essential Oils with Chitosan Films[J]. J Agric Food Chem, 2011, 59(23):12411-12419.

Preparation and Performance of Chitosan Grafted Polyvinyl Pyrrolidone Film with Iodine

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