应用化学 ›› 2023, Vol. 40 ›› Issue (10): 1376-1395.DOI: 10.19894/j.issn.1000-0518.230074
• 综合评述 • 上一篇
刘三荣1, 刘超2(), 赵卿波3, 赵洪福3, 毕吉福1()
收稿日期:
2023-03-24
接受日期:
2023-06-27
出版日期:
2023-10-01
发布日期:
2023-10-13
通讯作者:
刘超,毕吉福
基金资助:
San-Rong LIU1, Chao LIU2(), Qing-Bo ZHAO3, Hong-Fu ZHAO3, Ji-Fu BI1()
Received:
2023-03-24
Accepted:
2023-06-27
Published:
2023-10-01
Online:
2023-10-13
Contact:
Chao LIU,Ji-Fu BI
About author:
liuchaochem@tju.edu.cnSupported by:
摘要:
橡塑材料在运动鞋制造过程中被普遍应用,总结了运动鞋制造过程中天然橡胶、丁苯橡胶、丁腈橡胶、氯丁橡胶、顺丁橡胶、再生橡胶、聚氯乙烯、聚烯烃弹性体、苯乙烯-丁二烯-苯乙烯弹性体、乙烯-醋酸乙烯共聚物、聚氨酯和嵌段聚醚酰胺树脂等橡塑材料的基本性能。分类别综述了相关橡塑材料近年的研究进展。 指出未来运动鞋用橡塑材料将向着轻量化、功能化、智能化和环保化的方向发展。
中图分类号:
刘三荣, 刘超, 赵卿波, 赵洪福, 毕吉福. 运动鞋用橡塑材料的研究进展[J]. 应用化学, 2023, 40(10): 1376-1395.
San-Rong LIU, Chao LIU, Qing-Bo ZHAO, Hong-Fu ZHAO, Ji-Fu BI. Research Progress of Rubber and Plastic Materials for Athletic Shoes[J]. Chinese Journal of Applied Chemistry, 2023, 40(10): 1376-1395.
Shore hardness A | Density/(g·cm-3) | Tensile strength/MPa | Elongation at break/% | Tear strength /(N·mm-1) | Abrasive resistance/mm3 | Dry friction coefficient | Wet friction coefficient | |
---|---|---|---|---|---|---|---|---|
Sticky rubber sole | 60 | 1.120 | 15.5 | 568 | 16.1 | 87 | 1.28 | 1.02 |
Ordinary rubber sole | 59 | 1.16 | 12.9 | 581 | 12.9 | 155 | 0.94 | 0.68 |
表1 粘性橡胶底材与普通运动鞋橡胶底的性能对比[26]
Table 1 The performance comparison between adhesive rubber sole and ordinary sports rubber sole[26]
Shore hardness A | Density/(g·cm-3) | Tensile strength/MPa | Elongation at break/% | Tear strength /(N·mm-1) | Abrasive resistance/mm3 | Dry friction coefficient | Wet friction coefficient | |
---|---|---|---|---|---|---|---|---|
Sticky rubber sole | 60 | 1.120 | 15.5 | 568 | 16.1 | 87 | 1.28 | 1.02 |
Ordinary rubber sole | 59 | 1.16 | 12.9 | 581 | 12.9 | 155 | 0.94 | 0.68 |
Name of material | Formula 1 mass | Formula 2 mass | Formula 3 mass |
---|---|---|---|
Butadiene rubber | 5 | 7 | 8 |
Epoxidized natural rubber | 2 | 1.5 | 2.5 |
Hydrogenated butadiene-acrylonitrile rubber | 1 | 1 | 1.5 |
Homogenizing reagent | 0.105 | 0.116 | 0.15 |
Silane coupling agent | 0.35 | 0.2 | 0.4 |
Silica | 4 | 3.5 | 45 |
Al2O3 nano-particles | 0.5 | 1 | 1.2 |
Zinc oxide powders | 0.4 | 0.4 | 0.4 |
PEG | 0.4 | 0.4 | 0.45 |
ZnSt | 0.08 | 0.1 | 0.18 |
S | 0.2 | 0.2 | 0.2 |
Thiazole accelerator | 0.101 | 0.09 | 0.09 |
Thuiram accelerator | 0.66 | 0.06 | 0.06 |
Thioate accelerator | 0.033 | 0.03 | 0.03 |
Water-based viscosifying resin | 0.1 | 0.15 | 0.15 |
Softening oil | 0.2 | 0.2 | 0.3 |
Antiager | 0.18 | 0.18 | 0.2 |
Paraffin | 0.1 | 0.1 | 0.1 |
表2 鞋底用耐磨橡胶的配方表[48]
Table 2 Formula sheet for wear-resistant rubber[48]
Name of material | Formula 1 mass | Formula 2 mass | Formula 3 mass |
---|---|---|---|
Butadiene rubber | 5 | 7 | 8 |
Epoxidized natural rubber | 2 | 1.5 | 2.5 |
Hydrogenated butadiene-acrylonitrile rubber | 1 | 1 | 1.5 |
Homogenizing reagent | 0.105 | 0.116 | 0.15 |
Silane coupling agent | 0.35 | 0.2 | 0.4 |
Silica | 4 | 3.5 | 45 |
Al2O3 nano-particles | 0.5 | 1 | 1.2 |
Zinc oxide powders | 0.4 | 0.4 | 0.4 |
PEG | 0.4 | 0.4 | 0.45 |
ZnSt | 0.08 | 0.1 | 0.18 |
S | 0.2 | 0.2 | 0.2 |
Thiazole accelerator | 0.101 | 0.09 | 0.09 |
Thuiram accelerator | 0.66 | 0.06 | 0.06 |
Thioate accelerator | 0.033 | 0.03 | 0.03 |
Water-based viscosifying resin | 0.1 | 0.15 | 0.15 |
Softening oil | 0.2 | 0.2 | 0.3 |
Antiager | 0.18 | 0.18 | 0.2 |
Paraffin | 0.1 | 0.1 | 0.1 |
w(EVA)/% | w(EPDM)/ % | Foaming ratio | Dry friction coefficient | Wet friction coefficient | Abrasion/mm3 |
---|---|---|---|---|---|
100 | 0 | 165 | 0.46 | 0.4 | 624 |
92.5 | 7.5 | 160 | 0.5 | 0.41 | 512 |
85 | 15 | 156 | 0.56 | 0.44 | 527 |
77.5 | 22.5 | 150 | 0.59 | 0.47 | 541 |
70 | 30 | 146 | 0.65 | 0.49 | 501 |
表3 不同 EPDM 用量对 EVA 发泡材料的影响[95]
Table 3 The effects of EPDM content on property of foamed material[95]
w(EVA)/% | w(EPDM)/ % | Foaming ratio | Dry friction coefficient | Wet friction coefficient | Abrasion/mm3 |
---|---|---|---|---|---|
100 | 0 | 165 | 0.46 | 0.4 | 624 |
92.5 | 7.5 | 160 | 0.5 | 0.41 | 512 |
85 | 15 | 156 | 0.56 | 0.44 | 527 |
77.5 | 22.5 | 150 | 0.59 | 0.47 | 541 |
70 | 30 | 146 | 0.65 | 0.49 | 501 |
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