应用化学 ›› 2017, Vol. 34 ›› Issue (9): 1006-1016.DOI: 10.11944/j.issn.1000-0518.2017.09.170185

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金属有机骨架材料在轻烃分离中的应用

刘康ab,马鼎璇ab,施展b*()   

  1. a青岛科技大学化学与分子工程学院 山东 青岛 266042
    b吉林大学化学学院,无机合成与制备化学国家重点实验室 长春 130012
  • 收稿日期:2017-05-27 接受日期:2017-06-15 出版日期:2017-08-31 发布日期:2017-08-31
  • 通讯作者: 施展
  • 基金资助:
    国家自然科学基金(21371069,21601103)国家高技术研究发展计划(863计划)(2013AA031702)山东省自然科学基金(ZR2016BP04)青岛市创新源头计划(17-1-1-78-jch)资助课题

Application of Metal-Organic Frameworks for Separation of Hydrocarbon Mixtures

LIU Kangab,MA Dingxuanab,SHI Zhanb*()   

  1. aCollege of Chemistry and Molecular Engineering,Qingdao University of Science and Technology,Qingdao,Shandong 266042,China
    b State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry,Jilin University,Changchun 130012,China
  • Received:2017-05-27 Accepted:2017-06-15 Published:2017-08-31 Online:2017-08-31
  • Contact: SHI Zhan
  • Supported by:
    Supported by the Foundation of the National Natural Science Foundation of China(No.21371069, No.21601103), the National High Technology Research and Development Program(863 program) of China(No.2013AA031702), the Natural Science Foundation of Shandong Province, China(No.ZR2016BP04), the Scientific and Technical Development Project of Qingdao(No.17-1-1-78-jch)

摘要:

金属有机骨架材料(metal-organic frameworks,MOFs)是一种由金属离子或金属簇通过与有机配体自组装而形成的新型材料。 近年来,金属有机骨架材料在轻烃(包括甲烷、乙炔、乙烯、乙烷、丙烯和丙烷)分离方面引起了广泛兴趣。 本文简要地介绍了多种金属有机骨架材料分离不同轻烃气体的最新研究进展,并对影响分离效果的因素与研究前景进行了总结和展望。

关键词: 金属有机骨架材料, 轻烃, 分离

Abstract:

Metal-organic frameworks(MOFs) are a new class of porous materials formed by the self-assembly of metal ions(or metal clusters) and organic ligands. Currently, the application of metal-organic frameworks in separation of light hydrocarbons including methane, acetylene, ethylene, ethane, propylene and propane has attracted tremendous interests. This article briefly reviews the latest development in this field, and discusses the factors influencing the separation effect and the future study prospect.

Key words: metal-organic frameworks, light hydrocarbons, separation