改性活性炭负载氯化铁催化氧杂蒽衍生物的合成

doi:10.11944/j.issn.1000-0518.2015.03.140228

摘要/Abstract

摘要：

制备了一种新型改性活性炭负载FeCl₃催化剂(MAC-FeCl₃),并通过红外光谱及等离子体发射光谱等技术手段对其进行了表征。在MAC-FeCl₃催化下,β-萘酚与醛在PEG200中,于120 ℃反应60~120 min,合成了一系列氧杂蒽类衍生物,收率为79%~93%。该方法操作简单、产率高、环境友好。制备的催化剂性能稳定,使用4次仍保持较高活性。

关键词: 改性活性炭负载氯化铁, 氧杂蒽类衍生物, 异相催化

Abstract:

A novel modified active carbon supported ferric chloride catalyst(MAC-FeCl₃) has been prepared and characterized by IR and ICP-AES. In the presence of MAC-FeCl₃, condensation of aldehydes and β-naphthol was carried out in PEG 200 to afford a series of xanthene derivatives in 79%~93% yields within 60~120 min. The prepared catalyst can be recycled easily and the activity of catalyst maintains stable after used for 4 times. This affords this methodology the advantages on good yields, less pollution and simple work-up.

Key words: modified active carbon supported ferric chloride, xanthene derivatives, heterogeneous

中图分类号:

肖立伟, 高红杰, 任丽磊, 康健. 改性活性炭负载氯化铁催化氧杂蒽衍生物的合成[J]. 应用化学, 2015, 32(3): 304-309.

XIAO Liwei, GAO Hongjie, REN Lilei, KANG Jian. Synthesis of Xanthene Derivatives Catalyzed by Modified Active Carbon Supported Ferric Chloride[J]. Chinese Journal of Applied Chemistry, 2015, 32(3): 304-309.

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