有机胺存在下三苯基氯化锡与邻苯二甲酸反应合成离子型有机锡羧酸酯及产物杀菌活性

doi:10.11944/j.issn.1000-0518.2015.03.140212

摘要/Abstract

摘要：

在有机胺的存在下,三苯基氯化锡与邻苯二甲酸反应,得到了五配位阴离子型有机锡羧酸酯化合物,通过IR、¹H NMR、元素分析等技术手段对反应产物结构进行了表征,确定了反应产物的结构。同时测定了反应产物对10种病菌的杀菌活性,结果表明,产物对芦笋茎枯、花生褐斑、水稻曲病菌和黄瓜黑星病菌的杀死率均为100%,对其它病菌具有中等强度的杀死率。

关键词: 有机锡羧酸酯, 离子型有机锡羧酸酯, 杀菌活性

Abstract:

Penta-coordinated anionic organotin carboxylate compounds were synthesized by the reaction of Ph₃SnCl with HOOCC₆H₄COOH in the presence of organic amines. The products were characterized by elemental analysis, IR, and ¹H NMR spectroscopy. These compounds show good bactericidal activities for 10 bacteria. The mortality rates of the products are 100% for Phomopsis asparagi, Cercospora arachidicola Hoci, Ustilaginoidea virens and Cladosporium cucumerinum, and moderate for the orther bacteria.

Key words: organotin carboxylate, ionic organotin carboxylate, bactericidal activity

中图分类号:

钟桂云. 有机胺存在下三苯基氯化锡与邻苯二甲酸反应合成离子型有机锡羧酸酯及产物杀菌活性[J]. 应用化学, 2015, 32(3): 299-303.

ZHONG Guiyun. Synthesis of Anionic Organotin Carboxylate by the Reaction of Ph₃SnCl with o-Phthalic Acid under Organic Amines and Its Bactericidal Activity[J]. Chinese Journal of Applied Chemistry, 2015, 32(3): 299-303.

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