应用化学

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甘油的化学转化研究概况

乐传俊*,王丽,苏扬,朱少萍   

  1. (常州工学院理学院化工系 常州 213022)
  • 收稿日期:2013-04-26 修回日期:2013-07-14 出版日期:2014-04-10 发布日期:2014-04-10
  • 通讯作者: 乐传俊,副教授; Tel:0519-85135672; E-mail:ywangjung@163.com; 研究方向:精细有机催化合成和生物资源催化转化
  • 基金资助:
    江苏省自然科学基金项目(BK2011235),江苏省教育厅指导性项目(08kjd530001),常州工学院校级项目(YN0907)

Survey of the Chemical Transformation Progress of Glycerol

YUE Chuanjun*, WANG Li, SU Yang, ZHU Shaoping   

  1. (Chemical Engineering Department,School of Science,Changzhou Institute of
    Technology,Changzhou,Jiangsu 213022,China)
  • Received:2013-04-26 Revised:2013-07-14 Published:2014-04-10 Online:2014-04-10
  • Contact: YUE Chuan-Jun
  • Supported by:

    Supported by Nature Science Foundation of Jiangsu Province(No.BK2011235), Guiding Project of Education Department of Jiangsu Province(No.08kjd30001), and Nature Science Foundation of Changzhou Institute of Technology(No.YN0907)

摘要: 随着全球生物柴油产量的迅速增加,如何利用生物柴油副产的大量甘油已成为一个重要的研究课题。 生物源甘油是一个多功能的绿色“平台分子”,通过对其还原、氧化、重整(分解)、脱水、醚化及与其它试剂的反应可生成许多以石化为原料的产品。 本文概述了近年来由甘油转化为各种化工产品的研究进展。

关键词: 生物源甘油, 催化化学转化, 化学应用, 石化原料替代品

Abstract: With the rapid increase in biodiesel production, the utilization of a large surplus glycerol as a byproduct from biodiesel manufacture has become an important topic. Glycerol is a green multifunctional “platform molecule”. Products from the chemical transformation of glycerol through hydrogenolysis(reduction), oxidation, reforming(pyrolysis), dehydration, etherification and some compounds by reacting it with other reagents can replace those based on the petrochemical raw materials. The latest transformation progress of glycerol into other chemical products was reviewed in this article.

Key words: biomass glycerol, catalytic chemical conversion, chemical application, substitute for petrochemical materials

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