应用化学 ›› 2011, Vol. 28 ›› Issue (09): 1058-1062.DOI: 10.3724/SP.J.1095.2011.00607

• 研究论文 • 上一篇    下一篇

一种微乳酸体系的实验室研究

陈馥*,李茜璐,艾加伟,陈红均,魏云锦   

  1. (西南石油大学化学化工学院 成都 610500)
  • 收稿日期:2010-10-12 修回日期:2010-11-22 出版日期:2011-09-10 发布日期:2011-09-10
  • 通讯作者: 陈馥,教授; Tel:028-83037303; Fax:028-83037321; E-mail:chenfu@swpu.edu.cn; 研究方向:钻井完井液,油气田增产措施

Laboratory Research of One Micro-Emulsified Acid System

CHEN Fu*, LI Xilu, AI Jiawei, CHEN Hongjun, WEI Yunjin   

  1. (College of Chemistry and Chemical Engineering,Southwest Petroleum University,Chengdu 610500)
  • Received:2010-10-12 Revised:2010-11-22 Published:2011-09-10 Online:2011-09-10

摘要:

为降低酸化过程中酸液对油管和套管的腐蚀,增加酸液对地层的穿透距离,通过阳-非离子表面活性剂复配,成功制备了单相微乳土酸体系。 并得出了较优的实验室配方(质量分数):A-126 2.5%,CHJ-10 2.5%,正丁醇 1.2%,正辛醇 2.3%,W-221 0.5%,土酸 67.0%,柴油 24.0%。 通过添加适量的阴离子表面活性剂W-221,使体系在81 ℃保持了良好的热稳定性。 在室温和70 ℃下分别与P110S钢片反应,与同浓度的土酸相比,缓蚀率达到90.57%。 在70 ℃下与人造砂岩岩芯反应,溶蚀率降低到了0.5%。

关键词: 微乳酸, 表面活性剂, 缓蚀, 耐温

Abstract:

Single phase micro-emulsified acid was studied in laboratory aimed at reducing its corrosion on pipes in the process of acidizing and increasing the penetration range of the layer. Micro-emulsified acid were prepared by mixing cationic surfactant with nonionic surfactant and other additives. The laboratory formation of the single phase micro-emulsified mud acid were as following(mass ratio):2.5% A-126, 2.5% CHJ-100, 1.2% n-butanol, 2.3% n-octanol, 0.5% W-221, 67.0% mud acid, 24.0% diesel oil. The result shows that its thermal stability can reach 81 ℃ with the suitable amount of additive of anionic surfactant W-221. The reactions between the micro-emulsified acid and P110S steel under both room temperature and 70 ℃ showed that the ratio of inhibiting corrosion has reached to 90.57% compared with mud acid of the same concentrations. Finally, the reaction between the acid and manmade rock core under 70 ℃ shows that the corrosion rate reduce to 0.5%.

Key words: micro-emulsified acid, surfactant, corrosion inhibiting, temperature resistance

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