基于细乳液聚合的纳米颗粒制备与应用研究进展—撤稿（Withdrawed）

doi:10.11944/j.issn.1000-0518.2018.09.180174

摘要/Abstract

摘要：

细乳液聚合能够将多种材料封装在聚合物壳层中形成结构复杂的聚合物纳米颗粒。与普通乳液聚合技术相比,细乳液聚合具有方便、环保、粒径可控、稳定性高等优点。通过引入功能单体,可以很容易地实现对纳米颗粒的功能化。目前,细乳液聚合技术已经应用于很多领域,如纺织颜料的合成、粘接剂、分子印迹、磁性靶向纳米颗粒等。本文综述了近年关于细乳液聚合法合成纳米颗粒的各种应用。

2018年12月10日撤稿,链接地址：http://yyhx.ciac.jl.cn/CN/abstract/abstract17057.shtml

关键词: 细乳液聚合, 纳米颗粒, 封装, 应用

Abstract:

Various materials can be encapsulated with polymer to form nanoparticles with complex structures via miniemulsion polymerization. Miniemulsion polymerization has the advantages of convenience, environmental protection, controllable particle size and high stability compared with ordinary emulsion polymerization. Functionalization of nanoparticles can be easily realized by adding functional monomers. At present, miniemulsion polymerization technology has been applied to many fields, such as textile pigment, adhesives, molecular imprinting, magnetic targeting nanoparticles and so on. The applications of miniemulsion polymerization for the synthesis of nanoparticles in recent years are reviewed in this paper.

Key words: miniemulsion polymerization, nanoparticles, encapsulation, applications

中图分类号:

李晶晶, 樊江莉, 彭孝军. 基于细乳液聚合的纳米颗粒制备与应用研究进展—撤稿（Withdrawed）[J]. 应用化学, 2018, 35(9): 1026-1036.

LI Jingling, FAN Jiangli, PENG Xiaojun. Research Progress on Preparation and Applications of Nanoparticles Based on Miniemulsion Polymerization[J]. Chinese Journal of Applied Chemistry, 2018, 35(9): 1026-1036.

参考文献

[1]	Elgammal M,Prévost S,Schweins S,et al. Nanosized Latexes for Textile Printing Applications Obtained by Miniemulsion Polymerization[J]. Colloid Polym Sci,2014,292(7):1487-1500.
[2]	Yamamoto T,Kawaguchi K,Takahashi Y.Particle Size Control in the Soap-free Emulsion Polymerization of Styrene by an Oil-soluble Initiator with a Weakly Aacidic Water-soluble Initiator[J]. Colloids Surf A,2016,502:1-5.
[3]	Zhang Z,Susanne S,Ulrich Z. Alizarin Yellow R(AYR) as Compatible Stabilizer for Miniemulsion Polymerization[J]. J Colloid Interface Sci,2017,507:337-343.
[4]	Landfester K.Miniemulsion Polymerization and the Structure of Polymer and Hybrid Nanoparticles[J]. Angew Chem Int Ed,2009,48:4488-4507.
[5]	Antonietti M,Landfester K.Polyreactions in Miniemulsions[J]. Prog Polym Sci,2002,27:689-757.
[6]	Faucheu J,Gauthier C,Chazeau L,et al. Miniemulsion Polymerization for Synthesis of Structured Clay/Polymer Nanocomposites:Short Review and Recent Advances[J]. Polymer,2010,51:6-17.
[7]	Elgammal M,Schneider R,Gradzielski M.Development of Self-curable Hybrid Pigment Inks by Miniemulsion Polymerization for Inkjet Printing of Cotton Fabrics[J]. Dyes Pigm,2016,133:467-478.
[8]	Fu S,Tian A,Du C,et al. Preparation of Core Shell Latex for the Pigmented Ink of Textile Inkjet Printing[J]. J Appl Polym Sci,2013,127(4):2678-2683.
[9]	Abdou L A W,El-Molla M M,Hakeim O A,et al. Synthesis of Nanoscale Binders Through Miniemulsion Polymerization for Textile Pigment Applications[J]. Ind Eng Chem Res,2013,52(6):2195-2200.
[10]	Shen X,Zhou T,Ye L.Molecular Imprinting of Protein in Pickering Emulsion[J]. Chem Commun,2012,48:8198-8200.
[11]	Zhang N,Hu X,Guan P,et al. Preparation of Protein Imprinted Microspheres Using Amphiphilic Ionic Liquid as Stabilizer and Emulsifier via Miniemulsion Polymerization[J]. Chem Eng J,2017,317:356-367.
[12]	Fickert J,Makowski M,Kappl M,et al. Efficient Encapsulation of Self-healing Agents in Polymer Nanocontainers Functionalized by Orthogonal Reactions[J]. Macromolecules,2012,45(16):6324-6332.
[13]	Lu S,Forcada J.Preparation and Characterization of Magnetic Polymeric Composite Particles by Miniemulsion Polymerization[J]. Polym Chem-UK,2006,44(13):4187-4203.
[14]	Holzapfel V,Lorenz M,Weiss C K,et al. Synthesis and Biomedical Applications of Functionalized Fluorescent and Magnetic Dual Reporter Nanoparticles as Obtained in the Miniemulsion Process[J]. J Phys-Condens Mat,2006,18:2581-2594.
[15]	TAN Bien,ZHANG Lianzheng,HU Fang,et al. Preparation of Stable St/BA Miniemulsion[J]. Polym Mater Sci Eng,2001,2:80-83 (in Chinese). 谭必恩,张廉正,胡芳,等. 稳定苯乙烯/丙烯酸丁酯细乳液的制备[J]. 高分子材料科学与工程,2001,2:80-83.
[16]	Landfester K.Synthesis of Colloidal Particles in Miniemulsions[J]. Annu Rev Mater Res,2006,36:231-279.
[17]	Asua J M.Miniemulsion Polymerization[J]. Prog Polym Sci,2002,27(7):1283-1346.
[18]	Schork F J,Luo Y W,Smulders W,et al. Miniemulsion Polymerization[J]. Adv Polym Sci,2005,175:129-255.
[19]	Crespy D,Landfester K.Anionic Polymerization of ε-Caprolactam in Miniemulsion:Synthesis and Characterization of Polyamide-6 Nanoparticles[J]. Macromolecules,2005,38(16):6882-6887.
[20]	Weiss C K,Ziener U,Landfester K.A Route to Nonfunctionalized and Functionalized Poly(n-butylcyanoacrylate) Nanoparticles:Preparation in Miniemulsion[J]. Macromolecules,2007,40(4):928-938.
[21]	Cauvin S,Ganachaud F.On the Preparation and Polymerization of p-Methoxystyrene Miniemulsions in the Presence of Excess Ytterbium Triflate[J]. Macromol Symp,2004,215(1):179-190.
[22]	Cauvin S,Ganachaud F,Moreau M,et al. High Molar Mass Polymers by Cationic Polymerisation in Emulsion and Miniemulsion[J]. Chem Commun,2005,(21):2713-2715.
[23]	Soula R,Saillard B,Spitz R,et al. Catalytic Copolymerization of Ethylene and Polar and Nonpolar α-Olefins in Emulsion[J]. Macromolecules,2002,35(5):1513-1523.
[24]	Wehrmann P,Zuideveld M,Thomann R,et al. Copolymerization of Ethylene with 1-Butene and Norbornene to Higher Molecular Weight Copolymers in Aqueous Emulsion[J]. Macromolecules,2006,39(18):5995-6002.
[25]	Held A,Kolb I,Zuideveld M A,et al. Aqueous Polyketone Latices Prepared with Water-Insoluble Palladium(Ⅱ) Catalysts[J]. Macromolecules,2002,35(9):3342-3347.
[26]	Qumener D,Hroguez V,Gnanou Y.Latex Particles by Miniemulsion Ring-Opening Metathesis Polymerization[J]. Macromolecules,2005,38(19):7977-7982.
[27]	Qumener D,Hroguez V,Gnanou Y.Design of PEO-based Ruthenium Carbene for Aqueous Metathesis Polymerization. Synthesis by the “Macromonomer Method” and Application in the Miniemulsion Metathesis Polymerization of Norbornene[J]. Polym Chem-UK,2006,44(9):2784-2793.
[28]	Wehrmann P,Mecking S.Aqueous Dispersions of Polypropylene Andpoly(1-butene) with Variable Microstructures Formed with Neutral Nickel(Ⅱ) Complexes[J]. Macromolecules,2006,39(18):5963-5964.
[29]	Huber J,Mecking S.Aqueous Polyalkyne Dispersions[J]. Polym Mater Sci Eng,2007,96:306-307.
[30]	Pecher J,Mecking S.Nanoparticles from Step-Growth Coordination Polymerization[J]. Macromolecules,2007,40(22):7733-7735.
[31]	Landfester K,Montenegro R,Scherf U,et al. Semiconducting Polymer Nanospheres in Aqueous Dispersion Prepared by a Miniemulsion Process[J]. Adv Mater,2002,14(9):651-655.
[32]	Musyanovych A,Schmitz-Wienke J,Mailänder V,et al. Preparation of Biodegradable Polymer Nanoparticles by Miniemulsion Technique and Their Cell Interactions[J]. Macromol Biosci,2008,8(2):127-139.
[33]	Kietzke T,Neher D,Kumke M,et al. Phase Separation of Binary Blends in Polymer Nanoparticles[J]. Small,2007,3(6):1041-1048.
[34]	Schreiber E,Ziener U,Manske A,et al. Preparation of Narrowly Size Distributed Metal-Containing Polymer Latexes by Miniemulsion and Other Emulsion Techniques:Applications for Nanolithography[J]. Chem Mater,2009,21(8):1750-1760.
[35]	Manzke A,Phahler C H,Dubbers O,et al. Etching Masks Based on Miniemulsions:A Novel Route Towards Ordered Arrays of Surface Nanostructures[J]. Adv Mater,2007,19:1337-1341
[36]	Ramírez L,Antonietti M,Landfester K.Formation of Novel Layered Nanostructures from Lanthanide-Complexes by Secondary Interactions with Ligating Monomers in Miniemulsion Droplets[J]. Macromol Chem Phys,2006,207(2):160-165.
[37]	Holzapfel V,Musyanovych A,Landfester K,et al. Preparation of Fluorescent Carboxyl and Amino Functionalized Polystyrene Particles by Miniemulsion Polymerization as Markers for Cells[J]. Macromol Chem Phys,2005,206(24):2440-2449.
[38]	Lelu S,Novat C,Graillat C,et al. Encapsulation of an Organic Phthalocyanine Blue Pigment into Polystyrene Latex Particles Using a Miniemulsion Polymerization Process[J]. Polym Int,2003,52(4):542-547.
[39]	Bechthold N,Tiarks F,Willert M,et al. Miniemulsion Polymerization:Applications and New Materials[J]. Macromol Symp,2000,151(1):549-555.
[40]	Erdem B,Sudol E D,Dimonie V L,et al. Encapsulation of Inorganic Particles via Miniemulsion Polymerization.Ⅱ.Preparation and Characterization of Styrene Miniemulsion Droplets Containing TiO2 Particles[J]. Polym Chem-UK,2000,38(24):4431-4440.
[41]	Al-Ghamdi G H,Sudol E D,Dimonie V L,et al. Encapsulation of Titanium Dioxide in Styrene/n-Butyl Acrylate Copolymer by Miniemulsion Polymerization[J]. J Appl Polym Sci,2006,101(5):3479-3486.
[42]	Hoffmann D,Landfester K,Antonietti M.Encapsulation of Magnetite in Polymer Particles via the Miniemulsion Polymerization Process[J]. Magnetohydrodynamics,2001,37(3):217-221.
[43]	Fleischhaker F,Zentel R.Photonic Crystals from Core-Shell Colloids with Incorporated Highly Fluorescent Quantum Dots[J]. Chem Mater,2005,17(6):1346-1351
[44]	Esteves A C C,Bombalski L,Trindade T,et al. Polymer Grafting from CdS Quantum Dots via AGET ATRP in Miniemulsion[J]. Small,2007,3(7):1230-1236.
[45]	Cao Y,Reischmann S,Huber J,et al. Encapsulating of Single Quantum Dots into Polymer Particles[J]. Colloid Polym Sci,2008,286(11):1329-1334.
[46]	Bouanani R,Bendedouch D,Hemery P,et al. Encapsulation of Montmorillonite in Nanoparticles by Miniemulsion Polymerization[J]. Colloids Surf A,2008,317(1/3):751-755.
[47]	Diaconu G,Paulis M,Leiza J R.High Solids Content Waterborne Acrylic/Montmorillonite Nanocomposites by Miniemulsion Polymerization[J]. Macromol React Eng,2008,2(1):80-89.
[48]	Tiarks F,Landfester K,Antonietti M.Silica Nanoparticles as Surfactants and Fillers for Latexes Made by Miniemulsion Polymerization[J]. Langmuir,2001,17(19):5775-5780.
[49]	Monteil V,Stumbaum J,Thomann R,et al. Silica/Polyethylene Nanocomposite Particles from Catalytic Emulsion Polymerization[J]. Macromolecules,2006,39(6):2056-2062.
[50]	López-Martínez E I,Márquez-Lucero A,Hernández-Escobar C A,et al. Incorporation of Silver/Carbon Nanoparticles into Poly(merhyl methacrylate) via in Situ Miniemulsion Polymerization and Its Influence on the Glass-transition Temperature[J]. J Polym Sci Part B,2007,45(5):511-518.
[51]	Kim H,Daniels E S,Li S,et al. Polymer Encapsulation of Yttrium Oxysulfide Phosphorescent Particles via Miniemulsion Polymerization[J]. Polym Chem-UK,2007,45(6):1038-1054.
[52]	Bailly B,Donnenwirth A C,Bartholome C,et al. Silica-Polystyrene Nanocomposite Particles Synthesized by Nitroxide-Mediated Polymerization and Their Encapsulation Through Miniemulsion Polymerization[J]. J Nanomater,2006,76371:1-10.
[53]	Tiarks F,Landfester K,Antonietti M.Encapsulation of Carbon Black by Miniemulsion Polymerization[J]. Macromol Chem Phys,2001,202:51-60.
[54]	Steiert N,Landfester K.Encapsulation of Organic Pigment Particles via Miniemulsion Polymerization[J]. Macromol Mater Eng,2007,292(10/11):1111-1125.
[55]	Ramirez L P,Landfester K.Magnetic Polystyrene Nanoparticles with a High Magnetite Content Obtained by Miniemulsion Processes[J]. Macromol Chem Phys,2003,204(1):22-31.
[56]	ZHANG Wei.Development of Ink-jet Printing Technology[J]. Dyes Color,2005,42(6):9-12(in Chinese). 张伟. 喷墨打印技术的发展现状[J]. 染料与染色,2005,42(6):9-12.
[57]	Fu S,Tian A,Du C,et al. Preparation of Core-Shell Latex for the Pigmented Ink of Textile Inkjet Printing[J]. J Appl Polym Sci,2013,127(4):2678-2683.
[58]	Hakeim O A,Arafa A A,Zahran M K,et al. UV-curable Encapsulation of Surface-Modified Organic Pigments for Inkjet Printing of Textiles[J]. Colloids Surf A,2014,447:172 182.
[59]	Yoon B,Shin H,Yarimaga O,et al. An Inkjet-printable Microemulsion System for Colorimetric Polydiacetylene Supramolecules on Paper Substrates[J]. J Mater Chem,2012,22(17):8680-8686.
[60]	Taden A,Antonietti M,Heilig A,et al. Inorganic Films from Three Different Phosphors via a Liquid Coating Route from Inverse Miniemulsions[J]. Chem Mater,2004,16(24):5081-5087.