镍铁电池的工业应用及最新研究进展

doi:10.3724/SP.J.1095.2014.30353

摘要/Abstract

摘要： 镍铁电池具有安全环保、成本低廉和使用寿命长等优点，广泛应用于电网储能、备用电源等领域。此外，镍铁电池在电动汽车领域也表现出了良好的应用前景，受到许多国家的关注。本文介绍了镍铁电池的原理和结构设计。结合目前国内外镍铁电池的研发情况，概述了镍铁电池的综合性能和应用概况，重点围绕铁负极的问题，阐述了镍铁电池的研究现状与发展方向。

关键词: 镍铁电池, 爱迪生电池, 铁电极, 析氢反应

Abstract: The nickel-iron batteries have been widely employed into electricity grid and backup power devices owing to their low cost, durable in use, eco-friendliness and safety. Additionally, the promising nickel-iron battery is widely discussed for applications in electric vehicles(EV). The principle and structural design of nickel-iron battery were introduced, and combined with the current research and development situation of nickel-iron battery at home and abroad. The comprehensive performance and application of nickel-iron battery were overviewed, focusing on the existing problems of iron anode, research status as well as development direction of nickel-iron battery.

Key words: nickel-iron battery, Edison battery, iron anode, hydrogen evolution

中图分类号:

O646

姜巍, 吴耀明, 程勇, 王立民. 镍铁电池的工业应用及最新研究进展[J]. 应用化学, DOI: 10.3724/SP.J.1095.2014.30353.

JIANG Wei1,3, WU Yaoming1,2*, CHENG Yong1, WANG Limin1,2. Industrial Application of Nickel-Iron Battery and Its Recent Research Progress[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.30353.

参考文献

[1] Halpert G. Past Developments and the Future of Nickel Electrode Cell Technology[J]. J Power Sources,1984,12:177-192

[2] Chakkaravarthy C,Periasamy P,Jegannathan S,et al. The Nickel Iron Battery[J]. J Power Sources,1991,35:21-35

[3] Shukla A K,Ravikumar M K,Balasubramanian T S. Nickel/Iron Batteries[J]. J Power Sources,1994,51:29-36

[4] TAO Mingda,HE Xiuneng,PAN Wei. Iron Electrode Materials with High Capacity:CN,101645505A[P],2010-02-10(in Chinese).

陶明大,何秀能,潘唯. 高容量铁电极材料:中国,101645505A[P],2010-02-10.

[5] XIANG Min,WANG Lizhen. Research Status on Iron Electrode Used for Alkaline Battery[J]. Chinese Battery Ind,2000,5(4):170-174(in Chinese).

项民，王力臻. 碱性电池中铁负极的研究现状[J]. 电池工业，2000,5(4):170-174.

[6] Kao Chen-Yu,Chou Kan-Sen. Iron/carbon-Black Composite Nanoparticles as an Iron Electrode Material in a Paste Type Rechargeable Alkaline Battery[J]. J Power Sources,2010,195:2399-2404.

[7] HUANG Lihong. Hydrothermal Synthesis, Electrochemical Property and Charge/discharge Reaction Mechanism of α-Fe2O3 Anode in Lithium Ion Battery[D]. Chengdu:Sichuan University,2012(in Chinese).

黄丽宏. 锂离子电池负极材料α-Fe2O3的水热合成、电化学性能及反应机理研究[D]. 成都:四川大学,2012.

[8] Edison T A. Reversible Galvanic Battery:US Patent,0700136[P],1902-05-13.

[9] Edison T A. Can or Receptacle for Storage Batteries:US Patent,0857041[P],1907-06-18.

[10] Edison T A. Storage Batteries:US Patent,1379088[P],1921-05-24.

[11] Edison T A. Storage Batteries:US Patent,1526326[P],1925-02-17.

[12] Edison T A. Electrode for Batteries:US Patent,0704305[P],1902-07-08.

[13] Edison T A. Storage Batteries:US Patent,0896812[P],1908-08-25.

[14] Edison T A. Storage Batteries:US Patent,1377194[P],1921-05-10.

[15] Edison T A. Reversible Galvanic Battery:US Patent,0723450[P],1903-03-24.

[16] Edison T A. Reversible Galvanic Battery:US Patent,0727117[P],1903-05-05.

[17] Edison T A. Storage-Battery Electrode:US Patent,0948558[P],1910-02-08.

[18] Edison T A. Storage Battery:US Patent,1036471[P],1912-08-20.

[19] Edison T A. Electrolyte for Alkaline Storage Battery:US Patent,0876445[P],1908-01-14.

[20] YUAN Anbao,ZhANG Jianqing,CAO Chu′nan. Research Progress of Nickel Hydroxide Electrode[J]. Chinese J Power Sources,2001,25(1):53-59(in Chinese).

袁安保，张鉴清，曹楚南. 镍电极研究进展[J]. 电源技术,2001,25(1):53-59.

[21] ZHAO Fangyuan,ZHANG Baolin. Superparamagnetic Magnetite Nanoparticles Synthesized by Thermal Decomposition of Polyols and Their Properties[J]. Chinese J Appl Chem,2012,29(02):186-190(in Chinese).

赵方圆,张宝林. 醇热解法合成超顺磁性氧化铁纳米粒子及其性能[J]. 应用化学,2012,29(02):186-190.

[22] YANG Xiyun,GONG Zhuqing,PENG Changqing,et al. Formation Mechanism of Magnetite Prepared by Air Oxidation[J]. J Cent South Univ,2008,39(3):454-458(in Chinese).

杨喜云,龚竹青,彭长宏,等. 空气氧化法制备Fe3O4的反应机理[J]. 中南大学学报,2008,39(3):454-458.

[23] CHEN Rufen,ZHANG Yun,ZHAO Jianrong,et al. Synthesis of Variable-Sized Fe3O4 Nanocrystals and Their Magnetic Properties[J]. Chinese J Inorg Chem,2010,26(7):1207-1212(in Chinese).

陈汝芬,张云,赵建荣,等. 可控粒径纳米Fe3O4的制备及其磁性研究[J]. 无机化学学报,2010,26(7):1207-1212.

[24] LI Liangzhong,YU Lichun,LOU Helin,et al. Preparation Process of Iron Active Powder with High Capacity:CN 87105261A[P],1988-09-14(in Chinese).

李良忠,俞丽春,娄和林,等. 高容量活性铁粉制造方法:中国,87105261A[P],1988-09-14.

[25] Souradip M,Bo Yang,Manohar A K,et al. Self-Assembled Monolayers of n-Alkanethiols Suppress Hydrogen Evolution and Increase the Efficiency of Rechargeable Iron Battery Electrodes[J]. J Am Chem Soc,2012,135:347-353.

[26] Cerny J,Micka K. Voltammetric Study of an Iron Electrode in Alkaline Electrolytes[J]. J Power Sources,1989,25(2):111-122.

[27] Ojefors L. Self-Discharge of the Alkaline Iron Electrode[J]. Electrochim Acta,1976,21(4):263-266.

[28] Hang B T,Watanabe T,Egashira M,et al. The Effect of Additives on the Electrochemical Properties of Fe/C Composite for Fe/air Battery Anode[J]. J Power Sources,2006,155(2):461-469.

[29] Souza C A C,Carlos I A,Lopes M,et al. Self-Discharge of Fe-Ni Alkaline Batteries[J]. J Power Sources,2004,132(1/2):288-290.

[30] TAO Mingda，HE Xiuneng，PAN Wei. Iron Electrode Material with Low Self-Discharge Rate:CN 101651208A[P],2010-02-10(in Chinese).

陶明大,何秀能,潘唯. 低自放电铁电极材料：中国,101651208A[P],2010-02-10.

[31] LIN Dongfeng，Cai Rong，SONG Deying. Effect of the Content of Iron Powder in Iron Electrode on Its Charging Efficiency[J]. Chinese J Power Sources,2002,26(4):291-292(in Chinese).

林东风，蔡蓉，宋德瑛. 铁电极中铁粉含量对其充电效率的影响[J]. 电源技术，2002，26(04):291-292.

[32] Manohar A,Malkhandi S,Yang B,et al. A High-Performance Rechargeable Iron Electrode for Large-Scale Battery-Based Energy Storage[J]. J Electrochem Soc,2012,159:A1209-A1214

[33] LIN Dongfeng,CAO Jiansheng,YAN Tianying,et al. Preparation of Iron Electrode Active Powder and Study of Its High Rate Discharge Behavior[J]. Acta Sci Nat Univ Nakai,1999,32(2):26-29(in Chinese).

林东风，曹建胜，言天英，等. 铁电极活性粉的制备及其高倍率放电性能的研究[J]. 南开大学学报(自然科学)，1999，32(2):26-29.

[34] Wang H L,Liang Y Y,Gong M,et al. An Ultrafast Nickel-Iron Battery from Strongly Coupled Inorganic Nanoparticle/Nanocarbon Hybrid Materials[J]. Nat Commun,2012,3:917

[35] LV Mingxiang. Electrochemical Power Source[M]. Tianjin:Tianjin University Press,1992(in Chinese).

吕鸣祥,等. 化学电源[M]. 天津:天津大学出版社，1992.