中华医学超声杂志

应用化学 ›› 2011, Vol. 28 ›› Issue (06): 699-703.DOI: 10.3724/SP.J.1095.2011.00445

• 研究论文 • 上一篇    下一篇

氨基化镁铝类水滑石修饰电极及电化学杀菌

刘春秀,王萍,赵晶晶,陈传鹏,艾仕云*   

  1. (山东农业大学化学与材料科学学院 泰安 271018)
  • 收稿日期:2010-08-02 修回日期:2010-09-15 出版日期:2011-06-10 发布日期:2011-06-10
  • 通讯作者: 艾仕云，教授; Tel:0538-8249248; Fax:0538-8242251; E-mail:ashy@sdau.edu.cn; 研究方向：应用电化学
  • 基金资助:
    国家自然科学基金(20775044)山东省自然科学基金(Y2006B20)和国家大学生创新性实验计划(091043419)资助项目

Preparation of Amino-hydrotalcite Like Modified Electrode and Its Electrochemical Disinfection

LIU Chunxiu, WANG Ping, ZHAO Jingjing, CHEN Quanpeng, AI Shiyun*   

  1. (College of Chemistry and Material Science,Shandong Agricultural University,Tai′an 271018)
  • Received:2010-08-02 Revised:2010-09-15 Published:2011-06-10 Online:2011-06-10

PDF

1248

被引次数

8 | 1

摘要：

以层间插入十二烷基磺酸钠的镁铝类水滑石（Mg/Al-SDS-HTLc），与十六烷基三甲基溴化铵（CTAB）和3-氨丙基三乙氧基硅烷（APS）缩合反应制备了氨基化镁铝类水滑石（Mg/Al-NH2-HTLc）。 然后以Mg/Al-NH2-HTLc修饰热解石墨电极，通过循环伏安法探讨了该电极对吸附在其表面的大肠杆菌的杀灭作用。 结果表明，被吸附的大肠杆菌在经过循环伏安扫描后死亡率达到98.68%，大肠杆菌的死亡可能是由于细胞膜中易氧化物质（如鸟嘌呤）被氧化所致。

关键词: 氨基化类水滑石, 修饰电极, 大肠杆菌, 杀灭作用

Abstract:

Amino-hydrotalcite like compound(Mg/Al-NH2-HTLc) was prepared by Mg/Al-hydrotalcite like compounds by intercalating sodium dodecyl sulfate(Mg/Al-SDS-HTLc) followed by condensation reactions with hexadecyltrimethyl ammonium bromide(CTAB) and (3-aminopropyl)triethoxysilane(APS). Then, it was used to modify graphite electrode for the adsorption of Escherichia Coli(E.coli). Cyclic voltammetry(CV) was used to investigate the disinfection of the modified electrode. The result showed that the germicidal efficiency could reach to 98.68% and the possible disinfection mechanism might be the oxidation of the substance(such as guanine) within the membrane of E.coli.

Key words: Amino-Hydrotalcite Like, Modified Electrode, Escherichia Coli, Disinfection

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