应用化学 ›› 1997, Vol. 0 ›› Issue (4): 55-58.

• 研究论文 • 上一篇    下一篇

DCD/C4H9OH/LP/H2O体系溶致液晶的润滑性能

李干佐1, 沈强1, 马成松1, 刘维民2, 薛群基2   

  1. 1. 山东大学胶体和界面化学国家教委开放实验室, 济南 250100;
    2. 中国科学院兰州化学物理研究所, 兰州
  • 收稿日期:1996-12-31 修回日期:1997-05-05 出版日期:1997-08-10 发布日期:1997-08-10
  • 基金资助:
    国家自然科学基金

Lubrication of Lyotropic Liquid Crystals in DCD/C4H9OH/LP/H2O System

Li Ganzuo1, Shen Qiang1, Ma Chengsong1, Liu Weimin2, Xun Qiunji2   

  1. 1. Shandong University, Colloid andi Interface Chemistry Open Laboratory of Education Ministry, Jinan 250100;
    2. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou
  • Received:1996-12-31 Revised:1997-05-05 Published:1997-08-10 Online:1997-08-10

摘要: 测定了月桂酸二乙醇胺(DCD)/正丁醇(C4H9OH)/石腊油(LP)/水体系的相图。在液晶区选取两个样品点,用2H NMR技术和偏振光显微镜测定了这两样品点的微相结构。把液晶涂在铝合金表面测定不同负荷量下的磨痕宽度,并与十二羟基锂基脂等体系进行比较。结果表明,层状液晶在铝合金表面平行方向上的摩擦阻力较小,而在垂直方向上的负荷量高,是一种理想的润滑剂。

关键词: 月桂酸二乙醇胺, 正丁醇, 水, 石腊油, 溶致液晶, 润滑性能

Abstract: The phase diagram of the system of dodecyl carboxylic diethanolamine (DCD)/n-butanol (C4H9OH)/paraffin oil(LP)/water has been investigated. The phase structures of two points chosen from the liquid crystal phase region were determined by 2H NMR spectroscopy and polarized light microscope. The wear scar widths and the vertical loads of the two samples on the surface of aluminium alloy were measured and compared with those of water, paraffin oil, n-butanol, paraffin oil +2% n-butanol, paraffin oil+2%diethanolamine and lithium grease. The results indicate that the frictional force of the lamellar liquid crystal in the direction parallel to the surface of the alloy aluminium is very small, and the lamellar liquid crystal appear to be a good lubricant.

Key words: dodecyl carboxylic diethanolamine, butanol, paraffin oil, water, lyotropic liquid crystal, lubrication