中华医学超声杂志

应用化学 ›› 1997, Vol. 0 ›› Issue (1): 25-28.

• 研究论文 • 上一篇    下一篇

螺环单体的合成、聚合及与环氧树脂的固化反应

袁金颖1, 潘才元2, 白如科2   

  1. 1. 合肥工业大学化工学院 合肥 230009;
    2. 中国科学技术大学材料科学与工程系 合肥
  • 收稿日期:1996-04-23 修回日期:1996-09-17 出版日期:1997-02-10 发布日期:1997-02-10
  • 基金资助:
    国家自然科学基金

Synthesis, Cationic Polymerization and Curing Reaction with Epoxy Resin of a New Spiro Ortho Carbonate

Yuan Jinying1, Pan Caiyuan2, Bai Ruke2   

  1. 1. College of Chemical Engineering, University of Technology of Hefei, Hefei 230009;
    2. Department of Materials Science and Engineering, University of Science and Technology of China, Hefei
  • Received:1996-04-23 Revised:1996-09-17 Published:1997-02-10 Online:1997-02-10

PDF

585

被引次数

1

摘要： 合成了新螺环原碳酸酯单体:3,9-二(对甲氧基苄基)-1,5,7,11-四氧杂螺环[5,5]十一烷。以BF3·OEt2为催化剂,实现了其阳离子聚合。聚合产物的1H NMR、13C NMR、IR及元素分析均表明发生了双开环聚合反应。探讨了其聚合历程。用DSC和IR跟踪环氧树脂及其与螺环单体混合后的固化反应过程,研究了固化剂、反应条件对固化反应的影响

关键词: 螺环原碳酸酯, 阳离子聚合, 双开环聚合反应, 环氧树脂, 固化反应

Abstract: Anew spiro ortho carbonate 3,9-di(p-methoxybenzyl)1-1,5,7,11-tetroxaspiro[5,5] undecane(1)was prepared. Its cationic polymerization was carried out. The 1H NMR, 13C NMR and IR data as well as elemental analysis of the obtained polymers indicated that it underwent double ring opening polymerization. The polymerization mechanism was discussed. DSC and IR were used to trace the curing process of epoxy resin with or without this monomer. The effects of curing agent and curing condition on curing reaction were investigated.

Key words: spiro ortho carbonate, cationic polymerization, double ring-opening polymerization, epoxy resin, curing reaction

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