应用化学 ›› 1996, Vol. 0 ›› Issue (3): 107-108.

• 研究简报 • 上一篇    下一篇

C60和坚牢黑盐K的反应

王乃兴, 李纪生   

  1. 中国科学院化学研究所 北京 100080
  • 收稿日期:1995-10-18 修回日期:1995-12-25 出版日期:1996-06-10 发布日期:1996-06-10

Synthesis of a Fullerene Azobenzene Derivative

Wang Naixing, Li Jisheng   

  1. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080
  • Received:1995-10-18 Revised:1995-12-25 Published:1996-06-10 Online:1996-06-10

摘要: C60常规量制备成功以后,对其反应研究很广.C60分子结构中的 C=C 双健能够发生加成反应,这方面已有很多报道.本文通过 C60和具有偶氮苯骨架的坚牢黑盐 K 的反应,合成了C60的偶氮苯类衍生物.

关键词: C60衍生物, 坚牢黑盐 K, 加成反应

Abstract: A fullerene azobenzene derivative was synthesized by the reaction of C60with fast black K salt.The product was isolated by means of silica gel chromatography and identified by field desorption mass spectrometry and 13C NMR spectroscopy,UV spectrometry and IR spectroscopy.Some of theoretical analyses were given.

Key words: C60 derivative, fast black K salt, addition reaction