邻位取代1,2－二苯乙烯催化不对称二羟基化反应

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摘要： 近年催化的反式稀烃的不对称二轻基化反应取得明显进展^[1],但催化的邻位取代的1,2-二苯乙烯类化合物的不对称二经基化反应报道很少^[2].

Abstract: The asymmetric dihydroxylation of ortho-substituted 1,2-diphenylethenes affords the corresponding diols in good yields (77～89%) and high enantiomeric excesses (73～98%) in the presence of catalytic amount OsO₄ and four different chiral ligands respectively.

Key words: asymmetric dihydroxylation, chiral diol

张生勇, 孙晓莉. 邻位取代1,2－二苯乙烯催化不对称二羟基化反应[J]. 应用化学, 1996, 0(2): 70-72.

Zhang Shengyong, Sun Xiaoli. Catalytic Asymmetric Dihydroxylation of Ortho-Substituted 1, 2-Diphenylethenes[J]. Chinese Journal of Applied Chemistry, 1996, 0(2): 70-72.

邻位取代1,2－二苯乙烯催化不对称二羟基化反应

Catalytic Asymmetric Dihydroxylation of Ortho-Substituted 1, 2-Diphenylethenes

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