应用化学 ›› 1996, Vol. 0 ›› Issue (2): 73-75.

• 研究简报 • 上一篇    下一篇

高橡胶含量透明MBS合成及其对PVC的改性

高南, 肖贵斌, 胡伟军   

  1. 上海大学化学系 上海嘉定 201800
  • 收稿日期:1995-07-17 修回日期:1995-10-30 出版日期:1996-04-10 发布日期:1996-04-10

Synthesis of High Rubber Content Transparent MBS and the Modification for PVC Resins

Gao Nan, Xiao Guibin, Hu Weijun   

  1. Department of Chemistry, Shanghai University, JiadingShanghai 201800
  • Received:1995-07-17 Revised:1995-10-30 Published:1996-04-10 Online:1996-04-10

摘要: MBS(甲基丙烯酸甲酷一丁二烯一苯乙烯)树脂具有复杂的多相结构,可用作硬质聚氯乙烯(PVC)透明制品的抗冲改性剂[1,2].

关键词: MBS树脂, PVC树脂, 乳液聚合, 塑料增韧, 透射电镜

Abstract: High rubber content transparent MBS was synthesized via two-step emulsion graft polymerization. The effect of molecular weight regulator. rubber partcle size and rubber content on the mechanical and optical properties of MBS and PVS/MBS was investigated. MBS mixed with rubber particles of 1 μm (from bulk-suspension process) and 0.2 μm (from emilsion process) was used to modify PVC resin with satisfactory results. The morphology of PVC/MBS blends was studied by TEM.

Key words: MBS resin, PVC resin, emulsion polymerization, toughened plastics, TEM