应用化学 ›› 1994, Vol. 0 ›› Issue (5): 104-106.

• 研究论文 • 上一篇    下一篇

亚甲基二硝胺的杂环化和Mannich反应产物的合成

魏运洋, 吕春绪, 陆明, 王玉, 李志平   

  1. 南京理工大学化工学院 南京 210014
  • 收稿日期:1993-11-03 修回日期:1994-05-03 出版日期:1994-10-10 发布日期:1994-10-10

Products of Cyclisation and Mannich Condensation of Methylenedinitramine

Wei Yunyang, Lu Chunxu, Lu Ming, Wang Yu, Li Zhiping   

  1. Institute of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210014
  • Received:1993-11-03 Revised:1994-05-03 Published:1994-10-10 Online:1994-10-10

摘要: 由新的合成路线合成了亚甲基二硝胺;研究了亚甲基二硝胺的N-烷基化反应,分离出一种新的多硝基多氮杂三环氮杂环硝胺。改进了由亚甲基二硝胺合成3,7-二硝基-1,3,5,7-四氮杂[3.3.1]壬烷(DPT)的方法。

关键词: 高能量密度材料, 亚甲基二硝胺, N-烷基化反应, 环化, Mannich缩合反应

Abstract: Methylenedinitramine(1) was synthesized via a new route,N-alkylation of 1 gave a new polynitropolyazatricyclonitramine(2). An improved method for the synthesis of 3,7-dinitro-1,3,5,7-tetraazabicyclo[3.3.1]nonane(3,DPT) from 1 was proposed.

Key words: high energy density material, methylenedinitramine, N-alkylation, cyclization, Mannich condensation