广义aN指数及其应用 Ⅲ.酸性磷类和中性磷类萃取剂的广义aN指数与其物理性质的相关分析

摘要/Abstract

摘要： 本文将化合物的a_N指数扩展为广义a_N指数,并将其用于一些酸性和中性磷类萃取剂的纸上层析,比移值,校正保留时间,保留指数,纸上电泳泳动值及分子折射度等物理化学性质的相关性研究,取得了满意的结果。

关键词: 酸性磷类萃取剂, 中性磷类萃取剂, 相关分析, 广义a_N指数

Abstract: The concept of the general a_N index (GAI) has been derived from the a_N index, takinginto account the presence of the hetero atoms. In this paper the GAIs were calculated forsome acidic and neutral organophosphorus extractants. The correlations between the GAIs andthe physicochemical properties of these compounds have been investigated with satisfactoryresults, such as R_f value, corrected retention time, retention value in paper chromatography,mobility value in paper electrophoresis and molar refraction value.

Key words: acidic organophophorus extractant, neutral organophophorus extractant, genaral aN index, correlation analysis

王化云, 许禄, 苏锵. 广义a_N指数及其应用 Ⅲ.酸性磷类和中性磷类萃取剂的广义a_N指数与其物理性质的相关分析[J]. 应用化学, 1991, 0(6): 18-22.

Wang Huayun, Xu Lu, Su Qiang. THE GENERAL a_N INDEX AND ITS APPLICATIONS Ⅲ.THE CORRELATIONS BETWEEN GENARAL a_N INDEXES OF ORGANOPHOSPHORUS COMPOUNDS AND THEIR PHYSICOCHEMICAL PROPERTIES[J]. Chinese Journal of Applied Chemistry, 1991, 0(6): 18-22.

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