应用化学 ›› 1988, Vol. 0 ›› Issue (4): 12-16.

• 研究论文 • 上一篇    下一篇

苯胺的化学聚合

唐劲松, 王利祥, 景遐斌, 王宝忱, 王佛松   

  1. 中国科学院长春应用化学研究所
  • 收稿日期:1987-05-18 修回日期:1987-10-05 出版日期:1988-08-10 发布日期:1988-08-10
  • 基金资助:
    国家自然科学基金

CHEMICAL POLYMERIZATION OF ANILINE

Tang Jinsong, Wang Lixiang, Jing Xiabin, Wang Baochen, Wang Fosong   

  1. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1987-05-18 Revised:1987-10-05 Published:1988-08-10 Online:1988-08-10

摘要: 本文研究了氧化剂浓度、聚合溶液酸浓度、苯胺浓度以及氧化剂种类对苯胺化学氧化聚合的影响.结果表明,聚合条件的改变强烈地影响聚合物收率、电导率以及分子结构.本文初步给出了合成具有较高电导率聚苯胺的实验条件范围.

关键词: 聚苯胺, 氧化聚合, 高分子导体

Abstract: The effects of kinds of oxidants and the concentration of oxidant (NH42S)2O8, HC1 and monomer on aniline polymerization have been investigated. The products were characterized by FTIR,elemental analysis and conductivity measurements. The results show that the polymerization conditions affect not only the polymer yield, but also its conductivity and molecular structure. The experimental conditions to obtain the polyaniline with higher conductivity is outlined.

Key words: Polyaniline, Oxidative polymerization, Polymeric conductor