应用化学 ›› 1986, Vol. 0 ›› Issue (2): 58-63.

• 研究论文 • 上一篇    下一篇

稀土金属卟吩的红外光谱

王文韵, 羊彦衡, 张杰   

  1. 中国科学院长春应用化学研究所
  • 收稿日期:1984-12-13 修回日期:1985-03-22 出版日期:1986-04-10 发布日期:1986-04-10
  • 通讯作者: 王文韵

THE INFRARED SPECTRA OF RARE EARTH METALLOPORPHINS

Wang Wenyun, Yang Yanheng, Zhang Jie   

  1. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1984-12-13 Revised:1985-03-22 Published:1986-04-10 Online:1986-04-10

摘要: 测得了Ln(OCITPP)acac和Ln(TPP)acac两个系列稀土金属卟吩的4000—100cm-1波长范围的红外光谱,并作了归属。找出了苯环邻位氯取代的稀土金属卟吩与未取代对应物相比较在光谱上所出现的差异,并给予解释。

Abstract: The infrared spectra in the range of 4000-100cm-1 of rare earth complexes of tetrakis(o-chlorophenyl) porphin(OCITPP) and tetraphenylporphin(TPP)have been measured and assigned. The differences between the IR spectra of these ortho-chlorophenyl substituted and unsubstituted metalloporphins have been found and interpreted as well.