应用化学 ›› 1986, Vol. 0 ›› Issue (2): 64-66.
• 研究简报 • 上一篇 下一篇
洪华华, 王柔, 王先元, 卢全杰, 李广年
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Hong Huahua, Wang Rou, Wang Xianyuan, Lu Quanjie, Li Guangnian
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摘要： 亚铁卟啉络合物因其可逆键合分子氧的性能而受到人们的重视。基于生物体中的亚铁卟啉络合物的轴向位置键合有一定的基团,因而对于铁卟啉及其轴向配位体的研究较为活跃,但有关其催化性能方面的研究报导甚少。
Abstract: The catalytic activities of ironⅢ) porphyrins with an axially ligated imidazole(Im), 2-methylimidazole (MeIm), pyridine (Py), or 4-methylpyridine (MePy), for the selective oxidation of cyclohexane in the model system have been investigated. It has been found that with imidazole ligand, a strong donor, the catalytic activity of iron porphyrin is slightly higher than that of hemin. The catalytic activities of the complexes derease in the order of Hemin·Im≈Hemin·MeIm>Hemin·Py≈Hemin·MePy≈Hemin>ClFe(Ⅲ)TPP·Im>C1Fe(Ⅲ)TPP.
洪华华, 王柔, 王先元, 卢全杰, 李广年. 铁卟啉轴向配位络合物在环己烷氧化反应中的催化作用[J]. 应用化学, 1986, 0(2): 64-66.
Hong Huahua, Wang Rou, Wang Xianyuan, Lu Quanjie, Li Guangnian. THE CATALYTIC BEHAVIORS OF AXIAL COORDINATED COMPLEXES OF IRON(Ⅲ) PORPHYRINS IN THE OXIDATION REACTION OF CYCLOHEXANE[J]. Chinese Journal of Applied Chemistry, 1986, 0(2): 64-66.
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http://yyhx.ciac.jl.cn/CN/Y1986/V0/I2/64
