中华医学超声杂志

应用化学 ›› 2010, Vol. 27 ›› Issue (03): 276-279.DOI: 10.3724/SP.J.1095.2010.90241

• 研究论文 • 上一篇    下一篇

HAP/P(MMA-St)复合微球的制备及其吸附性能

徐惠*,刘小育,范宗良,张斯凡,苟国俊   

  1. (兰州理工大学 石油化工学院 兰州 730050)
  • 收稿日期:2009-04-07 修回日期:2009-07-01 出版日期:2010-03-10 发布日期:2010-03-10
  • 通讯作者: 徐惠，女，博士，教授; E-mail:xuhui@lut.cn; 研究方向：纳米功能复合材料
  • 基金资助:
    国家自然科学基金(50602020)和甘肃省自然基金(2007JS05348)资助项目

Preparation and Adsorption of  HAP/P(MMA-St) Polymeric Microspheres

XU Hui*, LIU Xiao-Yu, FAN Zong-Liang, ZHANG Shi-Fan, GOU Guo-Jun   

  1. (College of Petrochemical Technology,Lanzhou University of Technology,Lanzhou 730050)
  • Received:2009-04-07 Revised:2009-07-01 Published:2010-03-10 Online:2010-03-10
  • Contact: XU Hui

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摘要：

以微孔纳米羟基磷灰石（HAP）为无机载体，甲基丙烯酸甲酯（MMA）和苯乙烯（St）为聚合单体，采用悬浮聚合法制备了HAP/P(MMA-St)复合微球。研究了影响球体粒度及其分布的主要因素和微球的吸附性能。结果表明，表面活性剂用量（质量分数，下同）为1‰、MMA用量为2%，HAP用量为30%，转速为300r/min时复合微球的合格球收率最高为86.4%。当微球中HAP的含量为36.07%时，HAP/P(MMA-St)微球对牛血清蛋白的最大吸附量Qe=18.70 mg/g，比未加HAP时，增加了4.65 mg/g。

关键词: 羟基磷灰石，甲基丙烯酸甲酯，苯乙烯

Abstract:

Polymeric HAP/P(MMA-St) composite microspheres were synthesized via suspension polymerization with microporous hydroxyl apatite(HAP) nanomaterial as inorganic carrier, polymethyl methacrylate(MMA) and styrene(St) as monomers. The effects of main factors on the particle distribution and adsorption performance of polymeric HAP/P(MMA-St) composite microspheres were investigated. Experimental results show that a maximal yield of qualified microspheres of 86.4% could be achived when the mass fractions of surfactant, MMA and HAP were 10%, 20% and 30% accordingly under a rotation speed of 300 r/min.  The absorbability of polymeric microspheres for BSA was studied through a static adsorption process. When the mass fraction of HAP was 36.07%, adsorption quantity was Qe=18.70 mg/g, an increase of 4.65 mg/g could be observed compared to that without adding.

Key words: HAP, MMA, St

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