应用化学 ›› 2017, Vol. 34 ›› Issue (9): 979-995.DOI: 10.11944/j.issn.1000-0518.2017.09.170182

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微纳米金属有机骨架材料的制备及形貌调控

赵雪妍ab,‡,包守信b,‡,蔡学超bc,郑笑秋a*(),赵瑞雪a*(),李云辉a,逄茂林b*()   

  1. a长春理工大学化学与环境工程学院 长春 130022
    b中国科学院长春应用化学研究所,稀土资源利用国家重点实验室 长春 130022
    c中国科学院大学 北京 100049
  • 收稿日期:2017-05-27 接受日期:2017-06-09 出版日期:2017-08-31 发布日期:2017-08-31
  • 通讯作者: 郑笑秋,赵瑞雪,逄茂林
  • 基金资助:
    国家自然科学基金(21471145)吉林省科技发展计划项目(20170101179JC)

Size and Shape Controlled Growth of Micron or Nano Sized Metal Organic Frameworks

Xueyan ZHAOab,‡,Shouxin BAOb,‡,Xuechao CAIbc,Xiaoqiu ZHENGa*(),Ruixue ZHAOa*(),Yunhui LIa,Maolin PANGb*()   

  1. aSchool of Chemistry & Environmental Engineering,Changchun University of Science and Technology,Changchun 130022,China
    bState Key Laboratory of Rare Earth Resource Utilization,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China
    cUniversity of Chinese Academy of Sciences,Beijing 100049,China
  • Received:2017-05-27 Accepted:2017-06-09 Published:2017-08-31 Online:2017-08-31
  • Contact: Xiaoqiu ZHENG,Ruixue ZHAO,Maolin PANG
  • Supported by:
    Supported by the National Natural Science Foundation of China(No.21471145), the Science and Technology Development Planning Project of Jilin Province(No.20170101179JC),

摘要:

金属有机骨架材料(Metal-Organic Frameworks,MOFs)由于具有超高的比表面积和孔隙率、孔径大小和结构可调等优点,在能源、催化和生物医药等领域引起了人们广泛的重视。 近年来,微纳米MOFs的可控制备成为了一个新的研究热点。 本文总结了微纳米MOFs的合成方法、形貌调控以及应用方面的研究成果,并对其未来研究进行了展望。

关键词: 金属有机骨架材料, 微纳米, 形貌调控

Abstract:

Size and shape controlled growth of nano or micron sized metal-organic frameworks(MOFs) has attracted great attention in recent years. The ability to deliberately access monodisperse nano or microsized MOFs offers prospective applications in heterogeneous catalysis, porous membranes, thin-film devices, controlled drug release, and biomedical fields. This review highlights the recent development of size and shape controlled growth as well as the application of nano or micron sized MOFs, finally the future prospective is briefly addressed.

Key words: metal-organic frameworks, nano or micron size, size and shape control