应用化学

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卟啉微纳米材料的制备及应用研究进展

杨建东1,2,卢小泉2*   

  1. (1.陇南师范高等专科学校生物化学系 成县 742500;
    2.甘肃省生物电化学与环境分析重点实验室,西北师范大学 兰州 730070)
  • 收稿日期:2012-03-22 修回日期:2012-04-16 出版日期:2012-10-10 发布日期:2012-10-10
  • 通讯作者: 卢小泉,教授; Tel/Fax:0931-7975276; E-mail:Luxq@nwnu.edu.cn; 研究方向:功能化卟啉纳米材料与卟啉电化学
  • 基金资助:
    国家自然科学基金(2775060,20875077)资助项目,甘肃省教育厅科研项目(0928B02)

Recent Development in the Preparation and Application of Porphyrin Micro- and Nanomaterials

YANG Jiandong1,2, LU Xiaoquan2*   

  1. (1.Department of Biology & Chemistry,Longnan Normal College,Chengxian 742500,China;
    2.Key Laboratory of Bioelectrochemisty & Environmental Analysis of Gansu Province,Northwest Normal of University,Lanzhou 730070,China)
  • Received:2012-03-22 Revised:2012-04-16 Published:2012-10-10 Online:2012-10-10

摘要: 综述了卟啉微纳米材料合成的制备方法,以及将其作为传感、光电器件等应用的研究进展。 卟啉类化合物是广泛存在于自然界重要的生物分子,其独特的平面骨架和共轭大π结构,使之成为分子组装体系中优良的构筑基元。 制备的卟啉微纳米材料因其良好的光、热稳定性,已被广泛用于分析化学、仿生、催化及材料科学等领域。

关键词: 卟啉化合物, 微纳米材料, 制备方法, 应用

Abstract: Recent development in the preparation and application of porphyrin micro- and nanomaterials was summarized. Currently, a variety of methods for preparing organic nanomaterials have been used for the preparation of porphyrin micro- and nanomaterials, such as surfactants templating, re-precipitation and ultrasound methods. In addition, porphyrin molecules have been chosen as excellent building blocks for the assemblying in supermolecular chemistry due to their unique planar molecular skeleton and conjugated π-π bondings. Up to date, the research on organic nanomaterials has been mainly focused on the preparation of functional porphyrin micro- and nanomaterials in recent years. With excellent optical property and thermal stability, porphyrin micro- nanomaterials will show broadly potentials in application fields of analytical chemistry, biomimetics, catalysis and materials science fields.

Key words: Porphyrin compounds, Micro- and Nanomaterials, chemical synthesis, optoelectronic devices

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