Design and Application Research of Shape-Stabilized Phase Change Materials for Building Energy Conservation

doi:10.19894/j.issn.1000-0518.240173

Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (12): 1780-1789.DOI: 10.19894/j.issn.1000-0518.240173

• Full Papers • Previous Articles Next Articles

Design and Application Research of Shape-Stabilized Phase Change Materials for Building Energy Conservation

Jie-Wei HE¹(), Shao-Wei DUAN², Xiao-Chuan LI¹

^1.School of Architecture and Engineering，Shaoyang Polytechnic，Shaoyang 422000，China
^2.School of Civil Engineering，Central South University of Forestry and Technology，Changsha 410004，China

Received:2024-05-30 Accepted:2024-08-15 Published:2024-12-01 Online:2025-01-02
Contact: Jie-Wei HE
About author:373652240@qq.com
Supported by:
Shaoyang Science and Technology Bureau Project(2023ZD0145);Shaoyang Vocational and Technical College Teaching Research and Reform Project(23JG013);the Scientific Research Project of Hunan Provincial Department of Education(24B1123)

Abstract

Abstract:

Phase change energy storage materials have advantages such as high energy storage density， stable performance， recyclability and environmental friendliness， making them promising for wide applications in the field of construction. This paper focuses on the research of palm oil methyl ester-lauric acid eutectic phase change materials with white carbon black and dodecanol as stabilizers and SEBS as supporting materials. It investigates the influence of different material ratios on the phase transition temperature and latent heat of the phase change materials. Additionally， microencapsulation technology is employed to combine the palm oil methyl ester-lauric acid eutectic phase change materials with gypsum building materials， creating a phase change simulation room to explore its feasibility in the construction field. The research results show that when m （methyl palmitate）∶m（lauric acid）=6∶4， the phase transition temperature is 24.5~28.5 ℃ and the latent heat of phase transition is 172.0 kJ/kg， both of which are suitable for the construction field； The original enthalpy of phase change during the melting process of phase change materials is 172.0 kJ/kg， which changes to 167.3 kJ/kg after 200 cycles， and the thermal conductivity is 0.256 W/（m·K）； The simulated room without adding phase change materials heats up and cools down faster under simulated sunlight from infrared lamps than the simulated room with organic eutectic phase change materials. The addition of phase change energy storage materials has a significant regulating effect on indoor temperature in buildings.

Key words: Building energy conservation, Phase change materials, Microencapsulation technology, Temperature regulation

CLC Number:

O621

Jie-Wei HE, Shao-Wei DUAN, Xiao-Chuan LI. Design and Application Research of Shape-Stabilized Phase Change Materials for Building Energy Conservation[J]. Chinese Journal of Applied Chemistry, 2024, 41(12): 1780-1789.

Figures/Tables 16

References 14

1	张华民. 高效大规模化学储能技术研究开发现状及展望［J］. 电源技术， 2007（8）： 587-591.
	ZHANG H M. Research and development status and prospects of efficient large scale chemical energy storage technology‍［J］. Power Suppl Technol， 2007（8）： 587-591.
2	李国俭. 相变储能材料开发与封装技术研究进展［J］. 热力发电， 2023， 52（2）： 23-31.
	LI G J. Research progress in the development and packaging technology of phase change energy storage materials‍［J］. Therm Power Generation， 2023， 52（2）： 23-31.
3	陈中华，马丽丽，余飞. 有机相变储能材料及其复合化研究进展［J］. 化工新型材料， 2010（9）： 42-44， 64.
	CHEN Z H， MA L L， YU F. Research progress on organic phase change energy storage materials and their composites‍［J］. New Chem Mater， 2010（9）： 42-44， 64.
4	陈爱英，汪学英，曹学增. 相变储能材料的研究进展与应用［J］. 材料导报， 2003， 17（5）： 42-44， 72.
	CHEN A Y， WANG X Y， CAO X Z. Research progress and application of phase change energy storage materials‍［J］. Mater Rev， 2003， 17（5）： 42-44， 72.
5	曾关跃，高专，熊玉竹. 多壁碳纳米管负载银/微晶纤维素定型复合相变材料的制备及性能研究［J］. 材料导报， 2023（23）： 231-236.
	ZENG G Y， GAO Z， XIONG Y Z. Preparation and performance study of multi walled carbon nanotube loaded silver/microcrystalline cellulose shaped composite phase change materials［J］. Mater Introduct， 2023（23）： 231-236.
6	REDDY V J， AKHILA K， DIXIT P， et al. Thermal buffering performance evaluation of fatty acids blend/fatty alcohol based eutectic phase change material and simulation［J］. J Energy Storage， 2021， 38： 102499.
7	叶志林，魏婷，易红玲，等. 癸酸-棕榈酸/膨胀珍珠岩定型相变材料的制备与热性能［J］. 华东理工大学学报（自然科学版）， 2017， 43（4）： 495-500.
	YE Z L， WEI T， YI H L， et al. Preparation and thermal properties of decanoic palmitic acid/expanded perlite phase change materials［J］. J East China Univ Sci Technol （Nat Sci Ed）， 2017， 43（4）： 495-500.
8	舒钊，钟珂，肖鑫，等. 硅藻土基脂肪酸定型相变材料的制备与表征［J］. 硅酸盐学报， 2022， 50（6）： 1652-1660.
	SHU Z， ZHONG K， XIAO X， et al. Preparation and characterization of diatomaceous earth based fatty acid phase change materials［J］. J Chin Ceramic Soc， 2022， 50（6）： 1652-1660.
9	陈云博，李昕怡，毛志平，等. 纳米甲壳素基Pickering乳液辅助构筑相变微胶囊［J］. 日用化学工业（中英文）， 2022， 52（12）：1286-1292.
	CHEN Y B， LI X Y， MAO Z P， et al. Construction of phase change microcapsules assisted by nano chitin based Pickering lotion［J］. Daily Chem Ind （Eng Chin）， 2022， 52（12）： 1286-1292.
10	徐众，李军，吴恩辉，等. 添加提钒尾渣对膨胀石墨/石蜡复合相变材料稳定性和导电性的影响［J］. 应用化学， 2022， 39（3）： 461-469.
	XU Z， LI J， WU E H， et al. The effect of adding vanadium extraction tailings on the stability and conductivity of expanded graphite/paraffin composite phase change materials［J］. Chin J Appl Chem， 2022， 39（3）： 461-469.
11	XIANG B， YANG Z B， ZHANG J. ASA/SEBS/paraffin composites as phase change material for potential cooling and heating applications in building［J］. Polym Adv Technol， 2021， 32（1）： 420-427.
12	吴秋萍，蔡昆廷，王元康，等. Co/C微波吸收性能及Co/C-聚氨酯相变复合材料的微波-热转换性能［J］. 应用化学， 2021， 38（12）： 1588-1598.
	WU Q P， CAI K T， WANG Y K， et al. Microwave absorption performance of Co/C and microwave thermal conversion performance of Co/C-polyurethane phase change composite materials［J］. Chin J Appl Chem， 2021， 38 （12）： 1588-1598.
13	陈曦，郑楠，刘凌志，等. 长链烷酸接枝羟丙基纤维素相变材料的制备及其性能［J］. 应用化学， 2015， 32（5）： 535-541.
	CHEN X， ZHENG N， LIU L Z， et al. Preparation and properties of long-chain alkanoic acid grafted hydroxypropyl cellulose phase change materials［J］. Chin J Appl Chem， 2015， 32（5）： 535-541.
14	吴秋萍，蔡昆廷，王元康，等. Co/C微波吸收性能及Co/C-聚氨酯相变复合材料的微波-热转换性能［J］. 应用化学， 2021， 38（12）： 969-975.
	WU Q P， CAI K T， WANG Y K， et al. Microwave absorption performance of Co/C and microwave thermal conversion performance of Co/C-polyurethane phase change composite materials［J］. Chin J Appl Chem， 2021， 38（12）： 969-975.

No	m（raw material）/g∣w（raw material）/%
No	Na₂SO₄·10H₂O	Na₂HPO₄·12H₂O	KCl	CMC	Deionized water	Graphite
1	2.100∣19.4	6.303∣58.2	0.427∣3.9	0.500∣4.6	1.000∣9.2	0.500∣4.6
2	2.000∣20.1	6.000∣61.3	0.500∣5.1	0.090∣0.9	0.700∣7.2	0.500∣5.1
3	2.500∣23.2	6.500∣60.4	0.500∣4.6	0.070∣0.7	0.700∣6.5	0.500∣4.6

No	m（raw material）/g∣w（raw material）/%
No	Na₂SO₄·10H₂O	Na₂HPO₄·12H₂O	KCl	CMC	Deionized water	Graphite
1	2.100∣19.4	6.303∣58.2	0.427∣3.9	0.500∣4.6	1.000∣9.2	0.500∣4.6
2	2.000∣20.1	6.000∣61.3	0.500∣5.1	0.090∣0.9	0.700∣7.2	0.500∣5.1
3	2.500∣23.2	6.500∣60.4	0.500∣4.6	0.070∣0.7	0.700∣6.5	0.500∣4.6

No	m（raw material）/g∣w（raw material）/%
No	C₁₇H₃₄O₂	C₁₂H₂₄O₂	C₁₂H₂₆O	SiO₂	SEBS
1	1∣9.6	9∣86.5	0.1∣1.0	0.1∣1.0	0.2∣1.9
2	2∣19.2	8∣77.0	0.1∣1.0	0.1∣1.0	0.2∣1.9
3	3∣28.9	7∣67.3	0.1∣1.0	0.1∣1.0	0.2∣1.9
4	4∣38.5	6∣57.7	0.1∣1.0	0.1∣1.0	0.2∣1.9
5	5∣48.1	5∣48.1	0.1∣1.0	0.1∣1.0	0.2∣1.9
6	6∣57.7	4∣38.5	0.1∣1.0	0.1∣1.0	0.2∣1.9
7	7∣67.3	3∣28.9	0.1∣1.0	0.1∣1.0	0.2∣1.9
8	8∣77.0	2∣19.2	0.1∣1.0	0.1∣1.0	0.2∣1.9
9	9∣86.5	1∣9.6	0.1∣1.0	0.1∣1.0	0.2∣1.9

No	m（raw material）/g∣w（raw material）/%
No	C₁₇H₃₄O₂	C₁₂H₂₄O₂	C₁₂H₂₆O	SiO₂	SEBS
1	1∣9.6	9∣86.5	0.1∣1.0	0.1∣1.0	0.2∣1.9
2	2∣19.2	8∣77.0	0.1∣1.0	0.1∣1.0	0.2∣1.9
3	3∣28.9	7∣67.3	0.1∣1.0	0.1∣1.0	0.2∣1.9
4	4∣38.5	6∣57.7	0.1∣1.0	0.1∣1.0	0.2∣1.9
5	5∣48.1	5∣48.1	0.1∣1.0	0.1∣1.0	0.2∣1.9
6	6∣57.7	4∣38.5	0.1∣1.0	0.1∣1.0	0.2∣1.9
7	7∣67.3	3∣28.9	0.1∣1.0	0.1∣1.0	0.2∣1.9
8	8∣77.0	2∣19.2	0.1∣1.0	0.1∣1.0	0.2∣1.9
9	9∣86.5	1∣9.6	0.1∣1.0	0.1∣1.0	0.2∣1.9

No	Wax melting point/℃	m（raw material）/g∣w（raw material）/%
No	Wax melting point/℃	Wax	SEBS
1	20	16∣80.0	4∣20.0
2	32	16∣80.0	4∣20.0
3	48	16∣80.0	4∣20.0

Design and Application Research of Shape-Stabilized Phase Change Materials for Building Energy Conservation

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 16

References 14

Related Articles 4

Recommended Articles

Metrics

Comments

No	m（raw material）/g∣w（raw material）/%		Phase change material （piece）	m（raw material）/g∣w（raw material）/%		Phase change material （piece）
No	CaHPO₄·0.5H₂O	Deionized water	Phase change material （piece）	CaHPO₄·0.5H₂O	Deionized water	Phase change material （piece）
1	18.0∣57.1	13.5∣42.9	0	149.4∣57.1	112.1∣42.9	0
2	15.5∣57.2	11.6∣42.8	4	128.7∣57.2	96.3∣42.8	33
3	14.2∣57.0	10.7∣43.0	6	117.9∣57.0	88.8∣43.0	50
4	12.9∣56.8	9.8∣43.0	8	107.1∣56.8	81.4∣43.2	67

No	m（raw material）/g∣w（raw material）/%		Phase transition temperature/℃	Latent heat of phase transformation/（kJ·kg^-1）
No	C₁₇H₃₄O₂	C₁₂H₂₄O₂	Phase transition temperature/℃	Latent heat of phase transformation/（kJ·kg^-1）
1	1∣9.6	9∣86.5	34.5~41.5	187.0
2	2∣19.2	8∣77.0	31.0~37.5	184.0
3	3∣28.9	7∣67.3	28.0~36.0	181.0
4	4∣38.5	6∣57.7	26.5~33.5	178.0
5	5∣48.1	5∣48.1	25.5~32.0	175.0
6	6∣57.7	4∣38.5	24.5~28.5	172.0
7	7∣67.3	3∣28.9	23.5~27.5	169.0
8	8∣77.0	2∣19.2	21.5~24.5	166.0
9	9∣86.5	1∣9.6	/	163.0

Samples	λ/（W·m^-1·K^-1）
SiO₂·nH₂O	0.075
C₁₇H₃₄O₂-C₁₂H₂₄O₂	0.256
C₁₇H₃₄O₂-C₁₂H₂₄O₂/SiO₂	0.145

[1]	Zhong XU, Jun LI, En-Hui WU, Yan JIANG. Influence of Vanadium Tailings on the Thermal Stability and Electrical Conductivity of Expanded Graphite/ Paraffin Composite Phase Change Materials [J]. Chinese Journal of Applied Chemistry, 2022, 39(3): 461-469.
[2]	WU Qiu-Ping, CAI Kun-Ting, WANG Yuan-Kang, SUN Kai, YANG Jin-Bo, HAN Song-Bai, LIU Yun-Tao. Microwave Absorption Properties of Co/C and Microwave-Heat Conversion Properties of Co/C-Polyurethane Phase Change Composites [J]. Chinese Journal of Applied Chemistry, 2021, 38(12): 0-0.
[3]	WU Qiu-Ping, CAI Kun-Ting, WANG Yuan-Kang, SUN Kai, YANG Jin-Bo, HAN Song-Bai, LIU Yun-Tao. Microwave Absorption Properties of Co/C and Microwave-Heat Conversion Properties of Co/C-Polyurethane Phase Change Composites [J]. Chinese Journal of Applied Chemistry, 2021, 38(12): 1588-1598.
[4]	AN Pinping, LUO Fubin, HUANG Baoquan, XIAO Liren, QIAN Qingrong, LI Hongzhou, CHEN Qinghua. Properties of Thermal Conductivity Enhanced Polyethylene Glycol-Based Phase Change Composites [J]. Chinese Journal of Applied Chemistry, 2020, 37(1): 46-53.