Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (12): 1630-1642.DOI: 10.19894/j.issn.1000-0518.230203
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Ke-Xin YANG1,2, Jie ZHOU2, Yu-Shan HOU1,2, Yao-Wei ZHANG1, Chen YIN2,3, Dong-Hui XU2, Guang-Yang LIU2()
Received:
2023-07-13
Accepted:
2023-11-06
Published:
2023-12-01
Online:
2024-01-03
Contact:
Guang-Yang LIU
About author:
liuguangyang@caas.cnSupported by:
CLC Number:
Ke-Xin YANG, Jie ZHOU, Yu-Shan HOU, Yao-Wei ZHANG, Chen YIN, Dong-Hui XU, Guang-Yang LIU. Research Progress on Preparation and Adsorption of Water Pollutants of Bimetallic Metal-Organic Framework[J]. Chinese Journal of Applied Chemistry, 2023, 40(12): 1630-1642.
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URL: http://yyhx.ciac.jl.cn/EN/10.19894/j.issn.1000-0518.230203
Fig.2 (A) One-step microwave-assisted synthesis of Co/Zn-MOF[26]; (B) Mechanochemical synthesis of bimetallic CoZn-ZIF[31]; (C) Post-synthesis modification synthesis of Fe/Ni-MOF[35]; (D) Synthesis of Cu-TMA by in-situ metal substitution method[36]
Simple operation, high yield, high crystallinity, low cost, easy to form crystals with large specific surface area | The binding kinetics between the two metal ions and the ligands are different, resulting in an unstable topology of the obtained metal frameworks | Precise control of reaction conditions. Such as molar ratio, reaction time, solubility of metal ions and pH of the reactant solution, etc | ||
Microwave irradiation method | The use of electric or magnetic fields to induce high-speed collisions between charged particles to produce high-purity crystals | The crystal particles formed are too small and the cost and yield are not always proportional | The reaction conditions were controlled by changing the irradiation power, reaction time and temperature | |
Ambient stirring method | Fast and simple operation, avoids aggregation caused by in-situ solvent heat conditions, enables large-scale production | Poor stability performance | Strictly control the reaction conditions, such as the order of addition reaction time, etc | |
Metal-substitution method | MOFs materials that cannot be prepared by conventional methods can be obtained by substitution reaction | Incorporation of a second metal usually produces a fragile framework | Selection of metals with similar ionic radii and coordination geometries, similar reactivity, size, electronegativity |
Table 1 The advantages and disadvantages of the preparation methods of bimetallic MOFs
Simple operation, high yield, high crystallinity, low cost, easy to form crystals with large specific surface area | The binding kinetics between the two metal ions and the ligands are different, resulting in an unstable topology of the obtained metal frameworks | Precise control of reaction conditions. Such as molar ratio, reaction time, solubility of metal ions and pH of the reactant solution, etc | ||
Microwave irradiation method | The use of electric or magnetic fields to induce high-speed collisions between charged particles to produce high-purity crystals | The crystal particles formed are too small and the cost and yield are not always proportional | The reaction conditions were controlled by changing the irradiation power, reaction time and temperature | |
Ambient stirring method | Fast and simple operation, avoids aggregation caused by in-situ solvent heat conditions, enables large-scale production | Poor stability performance | Strictly control the reaction conditions, such as the order of addition reaction time, etc | |
Metal-substitution method | MOFs materials that cannot be prepared by conventional methods can be obtained by substitution reaction | Incorporation of a second metal usually produces a fragile framework | Selection of metals with similar ionic radii and coordination geometries, similar reactivity, size, electronegativity |
Fig.3 (A) Schematic of the MSPE procedure for BUs from tea beverages and juice samples based on Fe3O4@MOF-808[48]; (B) XRD patterns of Fe3O4@MOF-808, MOF-808 and Fe3O4[48]; (C) The effect of recycle times of Fe3O4@MOF-808 on the recoveries of BUs[48]; (D) Comparison of the recoveries of Fe3O4@MOF-808 with commercial C18 sorbent for BUs[48]
Fig.4 (A) The preparation process of the Fe/Zr-MOFs[57]; (B) Removal rate of Fe/Zr-MOFs[57]; (C) Reusability of Fe/Zr-MOFs for the removal of DC[57]; (D) The adsorption mechanism of CR by Fe/Zr-MOFs[57]
Fig.5 (A) ?SEM images of ZIF-ZnCo-8∶?1[69]?; (B) FT-IR and XRD of ZIF-ZnCo-8∶?1 before and after photocatalytic[69]; (C) Photocatalytic performances of ZIF-ZnCo to Cr6+ and mixed of Cr6+ and CR[69]
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