Research Progress on Preparation and Adsorption of Water Pollutants of Bimetallic Metal-Organic Framework

doi:10.19894/j.issn.1000-0518.230203

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (12): 1630-1642.DOI: 10.19894/j.issn.1000-0518.230203

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Research Progress on Preparation and Adsorption of Water Pollutants of Bimetallic Metal-Organic Framework

Ke-Xin YANG¹^,², Jie ZHOU², Yu-Shan HOU¹^,², Yao-Wei ZHANG¹, Chen YIN²^,³, Dong-Hui XU², Guang-Yang LIU²()

^1.College of Horticulture and Landscape Architecture，Northeast Agricultural University，Harbin 150030，China
^2.Institute of Vegetables and Flowers，Chinese Academy of Agricultural Sciences，Beiing 100081，China
^3.College of Agriculture，Forestry and Technology，Hebei North University，Zhangjiakou 075132，China

Received:2023-07-13 Accepted:2023-11-06 Published:2023-12-01 Online:2024-01-03
Contact: Guang-Yang LIU
About author:liuguangyang@caas.cn
Supported by:
the National Key Research and Development Program of China(2022YFF0606800);the Special Fund of the Construction of the National Modern Agricultural Technology Industrial System(CARS-23-E03)

Abstract

Abstract:

Recently， with the advance of agriculturalization， industrialization and urbanization， pollutants such as pesticides， veterinary drugs， heavy metal ions and dyes emitted from various industries have brought great harm to the ecological environment and human production and life. Therefore， it is important to adopt green and efficient methods to remove pollutants. Metal-organic framework （MOFs） is a kind of porous crystalline material composed of metal ions and organic ligands， which has the advantages of adjustable pore size and large specific surface area， and has a wide range of applications in various fields. However， while monometallic MOFs have excellent performance but small pores and few active sites， bimetallic MOFs formed by introducing a second metal ion have the advantages of abundant pores， large specific surface area， tunable structure and abundant active sites. Recently， they have been widely used in catalysis， storage， drug loading， and transportation. The increased adsorption sites and enhanced synergistic effects make the bimetallic organic frameworks materials potentially promising for applications in the field of adsorption. Therefore， this paper summarizes recent research progress on bimetallic MOFs， discusses the challenges that face in terms of synthesis and applications， and looks forward to their further development， providing references for the fabrication of bimetallic MOFs and applications in pollutant adsorption.

Key words: Metal-organic frameworks （MOFs）, Bimetallic MOFs, Pollutants, Adsorption removal

CLC Number:

O647.3

Ke-Xin YANG, Jie ZHOU, Yu-Shan HOU, Yao-Wei ZHANG, Chen YIN, Dong-Hui XU, Guang-Yang LIU. Research Progress on Preparation and Adsorption of Water Pollutants of Bimetallic Metal-Organic Framework[J]. Chinese Journal of Applied Chemistry, 2023, 40(12): 1630-1642.

Figures/Tables 6

References 69

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Preparation method	Advantage	Disadvantage	Solution	Ref.
Solvothermal method	Simple operation， high yield， high crystallinity， low cost， easy to form crystals with large specific surface area	The binding kinetics between the two metal ions and the ligands are different， resulting in an unstable topology of the obtained metal frameworks	Precise control of reaction conditions. Such as molar ratio， reaction time， solubility of metal ions and pH of the reactant solution， etc	［40］
Microwave irradiation method	The use of electric or magnetic fields to induce high-speed collisions between charged particles to produce high-purity crystals	The crystal particles formed are too small and the cost and yield are not always proportional	The reaction conditions were controlled by changing the irradiation power， reaction time and temperature	［41］
Ambient stirring method	Fast and simple operation， avoids aggregation caused by in-situ solvent heat conditions， enables large-scale production	Poor stability performance	Strictly control the reaction conditions， such as the order of addition reaction time， etc	［42］
Metal-substitution method	MOFs materials that cannot be prepared by conventional methods can be obtained by substitution reaction	Incorporation of a second metal usually produces a fragile framework	Selection of metals with similar ionic radii and coordination geometries， similar reactivity， size， electronegativity	［43］

Preparation method	Advantage	Disadvantage	Solution	Ref.
Solvothermal method	Simple operation， high yield， high crystallinity， low cost， easy to form crystals with large specific surface area	The binding kinetics between the two metal ions and the ligands are different， resulting in an unstable topology of the obtained metal frameworks	Precise control of reaction conditions. Such as molar ratio， reaction time， solubility of metal ions and pH of the reactant solution， etc	［40］
Microwave irradiation method	The use of electric or magnetic fields to induce high-speed collisions between charged particles to produce high-purity crystals	The crystal particles formed are too small and the cost and yield are not always proportional	The reaction conditions were controlled by changing the irradiation power， reaction time and temperature	［41］
Ambient stirring method	Fast and simple operation， avoids aggregation caused by in-situ solvent heat conditions， enables large-scale production	Poor stability performance	Strictly control the reaction conditions， such as the order of addition reaction time， etc	［42］
Metal-substitution method	MOFs materials that cannot be prepared by conventional methods can be obtained by substitution reaction	Incorporation of a second metal usually produces a fragile framework	Selection of metals with similar ionic radii and coordination geometries， similar reactivity， size， electronegativity	［43］

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Research Progress on Preparation and Adsorption of Water Pollutants of Bimetallic Metal-Organic Framework

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