Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (3): 449-459.DOI: 10.19894/j.issn.1000-0518.220296
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Nan-Yu LIN, Feng GAO(
), Jiang-Ying QU, Jing-Jing TU, Wei-Jun ZHONG, Yun-Hao ZANG
Received:2022-09-02
Accepted:2023-02-18
Published:2023-03-01
Online:2023-03-27
Contact:
Feng GAO
About author:fenggao2003@163.comSupported by:CLC Number:
Nan-Yu LIN, Feng GAO, Jiang-Ying QU, Jing-Jing TU, Wei-Jun ZHONG, Yun-Hao ZANG. Preparation of Super-hydrophilic/Underwater Oil-phobic High Silicon Cloth and Its Oil-water Separation Performance[J]. Chinese Journal of Applied Chemistry, 2023, 40(3): 449-459.
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URL: http://yyhx.ciac.jl.cn/EN/10.19894/j.issn.1000-0518.220296
Fig.1 Schematic of synthetic procedures of APTES/SiO2/PDA@HSC
Fig.2 SEM images of HSC surfaces （A， B， C） and APTES/50 nm SiO2/PDA@HSC surface （D， E， F）
Fig.3 The EDS mapping for APTES/50 nm SiO2/PDA@HSC and the element content of C、N、O and Si
Fig.4 FT-IR spectra of pure HSC and APTES/SiO2/PDA@HSC
Fig.5 Water contact angle images of HSC（A）， APTES@HSC（B）， APTES/50 nm SiO2@HSC（C） and APTES/50 nm SiO2/PDA@HSC（D）
Fig.6 Underwater oleophobic test of HSC （A， B， C） and APTES/50 nm SiO2/PDA@HSC （D， E， F）
Fig.7 The separation process of the gasoline-water mixture on HSC（A， B） and APTES/50 nm SiO2/PDA@HSC（C， D）
Fig.8 （A） UV-Vis scan of gasoline-water mixture separation filter after extraction； （B） Oil content of filter and separation efficiency； （C） Membrane flux of water and gasoline-water mixture of HSC， 50 nm SiO2/PDA@HSC， APTES/50 nm SiO2@HSC， APTES/PDA@HSC and APTES/50 nm SiO2/PDA@HSC
| Oil-water flux/（L·m-2·h-1） | Pure water flux/（L·m-2·h-1） | Ref. | |
|---|---|---|---|
| 1 | — | 6 369 | ［ |
| 2 | 1389±67 | — | ［ |
| 3 | — | 9 700 | ［ |
| 4 | 762 | — | ［ |
| 5 | 1720±20 | — | ［ |
| 6 | 7184 | 11 465 | This work |
Table 1 Comparison of membrane flux between this work and other work
| Oil-water flux/（L·m-2·h-1） | Pure water flux/（L·m-2·h-1） | Ref. | |
|---|---|---|---|
| 1 | — | 6 369 | ［ |
| 2 | 1389±67 | — | ［ |
| 3 | — | 9 700 | ［ |
| 4 | 762 | — | ［ |
| 5 | 1720±20 | — | ［ |
| 6 | 7184 | 11 465 | This work |
Fig.9 （A） UV-Vis scan of gasoline-water mixture separation filter after extraction， （B） oil content of filter and separation efficiency and （C） membrane flux of water and gasoline-water mixture of HSC and APTES/x nm SiO2/PDA@HSC（x=50，300，500）
Fig.10 Membrane surfaces after gasoline-water mixture separation （gasoline incarnadined by oil red O） （A）HSC， （B） APTES/50 nm SiO2/PDA@HSC， （C） APTES/300 nm SiO2/PDA@HSC， （D） APTES/500 nm SiO2/PDA@HSC， （E， F） are the Wenzel state and Cassie-Baxter′s state of underwater oil contact angle， respectively
Fig.11 Gasoline-water mixture separation efficiency of 10 cycles by APTES/50 nm SiO2/PDA@HSC
Fig.12 （A，B） Peanut oil and （C，D） pump oil separation process of the oil-water mixture by APTES/50 nm SiO2/PDA@HSC
Fig.13 HSC and APTES/50 nm SiO2/PDA@HSC separation fluxes and separation efficiency of peanut oil-water and pump oil-water mixtures
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