Highly Selective Recognition of a Long-Chain Alkoxyphenylhydrozone Derivative for Floride Ion

doi:10.11944/j.issn.1000-0518.2020.12.200168

Chinese Journal of Applied Chemistry ›› 2020, Vol. 37 ›› Issue (12): 1432-1440.DOI: 10.11944/j.issn.1000-0518.2020.12.200168

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Highly Selective Recognition of a Long-Chain Alkoxyphenylhydrozone Derivative for Floride Ion

CAO Cheng^a,b, LIU Zhiyu^c, JI Xiangdong^a*, SHAO Xiaoxiao^a, XIAO Hong^a

^aKey Laboratory of Hexi Corridor Resources Utilization of Gansu, College of Chemistry and Chemical Engineering;^bKaiyuan Bio-Tech Development Center;^cZhangye People's Hospital Affiliated to Hexi University,Hexi University,Zhangye,Gansu 734000,China

Received:2020-06-03 Revised:2020-07-07 Accepted:2020-08-06 Published:2020-12-01 Online:2020-12-07
Contact: JI Xiangdong, associate professor; Tel/Fax:0936-8282066; E-mail:jxdsn@163.com; Research interests:synthesis and application of ion recognition receptor
Supported by:
National Natural Science Foundation of China(No.21761011), the Gansu Provincial Science and Technology Program Funded Project(No.18JR3RG205) and the Scientific Research Foundation of the Higher Education Institutions of Gansu Province(No.2018A-088)

Abstract

Abstract: A new long-chain alkoxyphenylhydrozone derivative, 1-(2,4-dinitrophenyl)-2-(4-(tetradecyloxy) benzylidene) hydrazine, was designed and synthesized. The ultraviolet-visible (UV-Vis) spectra and naked-eye recognition property of the receptor R for nine kinds of anions (F^-, Cl^-, Br^-, I^-, HSO^-₄, NO^-₃, ClO^-₄, H₂PO^-₄, Ac^-) were studied. The results indicate that the receptor R shows high UV-Vis and naked-eye recognition property towards F^-, Ac^- and H₂PO^-₄ in dimethylsulfoxide (DMSO) solution. Single colorimetric recognition of F^- is found by UV-Vis analysis and naked-eye recognition in H₂O/DMSO (1/9) solution, and the LOD (limit of detection) of receptor R for F^- is 7.02×10^-7 mol/L. The naked recognition paper of receptor R is prepared, and the Job's plot indicates the formation of complex between receptor R and F^- is in 1∶1 stoichiometric ratios. The recognition mechanism of receptor R is the “hydrogen-bond” recognition.

Key words: Schiff base receptor, ion detection, chemosensor for floride ion, naked-eye detection, anions

CLC Number:

O657.

CAO Cheng, LIU Zhiyu, JI Xiangdong, SHAO Xiaoxiao, XIAO Hong. Highly Selective Recognition of a Long-Chain Alkoxyphenylhydrozone Derivative for Floride Ion[J]. Chinese Journal of Applied Chemistry, 2020, 37(12): 1432-1440.

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Highly Selective Recognition of a Long-Chain Alkoxyphenylhydrozone Derivative for Floride Ion

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