Synthesis and Properties of Super-high Temperature Diketone Anhydride Polyimides

doi:10.11944/j.issn.1000-0518.2019.06.180352

Chinese Journal of Applied Chemistry ›› 2019, Vol. 36 ›› Issue (6): 658-663.DOI: 10.11944/j.issn.1000-0518.2019.06.180352

• Full Papers • Previous Articles Next Articles

Synthesis and Properties of Super-high Temperature Diketone Anhydride Polyimides

LIU Yongjun,ZHOU Liyun,SHENG Shouri,SONG Cheng(),HOU Haoqing,SONG Caisheng

College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330022,China

Received:2018-11-06 Accepted:2019-01-14 Published:2019-06-01 Online:2019-06-03
Contact: SONG Cheng
Supported by:
Supported by the National Natural Science Foundation of China(No.51663011), Science and Technology Research Project of Jiangxi Provincial Department of Education(No.GJJ170177)

Abstract

Abstract:

A novel diketone anhydride polyimide was synthesized by introducing p-phenylenediamine(PPD) to 4,4'-terephthaloyldiphthalic anhydride through the traditional two-step method in dimethylacetamide(DMAc). The properties of the polyimide were characterized by Fourier transform infrared spectrometer(FT-IR), wide-angle X-ray diffraction(WAXD), differential scanning calorimetric(DSC), dynamic thermomechanical analyzer(DMA), thermal gravimetric analysis(TGA), tensile test and ultraviolet-visible spectrophotometry(UV-Vis). The relationship between different thermal imidization temperature and the properties of the diketone polyimide was studied. The results showed that PAA formed the imide ring structure completely at 320 ℃. The polyimide had good film-forming performance and partially ordered aggregate structure. The polyimide had excellent thermal properties: the glass transition temperature(T_g) was 298 ℃ and the thermal decomposition temperature(T_5%) was 523 ℃. The film had a tensile strength of 130 MPa and tensile modulus of 5.77 GPa at 320 ℃. The cutoff wavelength of the film was 375 nm and the film had good transmittance in visible region.

Key words: diketone anhydride polyimide, thermal properties, transmittance

LIU Yongjun, ZHOU Liyun, SHENG Shouri, SONG Cheng, HOU Haoqing, SONG Caisheng. Synthesis and Properties of Super-high Temperature Diketone Anhydride Polyimides[J]. Chinese Journal of Applied Chemistry, 2019, 36(6): 658-663.

References

[1]	WANG Jiaming.Technology Advances and Market Prospects of Polyimide Film[J]. Synth Technol Appl,2012,37(3):24-29(in Chinese). 汪家铭. 聚酰亚胺薄膜技术进展与市场前景[J]. 合成技术及应用,2012,37(3):24-29.
[2]	Min C Y,Liu D D,He Z B,et al. Preparation of Novel Polyimide Nanocomposites with High Mechanical and Tribological Performance Using Covalent Modified Carbon Nanotubes via Friedel-Crafts Reaction[J]. Polymer,2018,150:223-231.
[3]	Cheng Y,Dong J,Yang C R,et al. Synthesis of Poly(benzobisoxazole-co-imide) and Fabrication of High-Performance Fibers[J]. Polymer,2017,133:50-59.
[4]	Chen D,Zhu H,Liu T.In Situ Thermal Preparation of Polyimide Nanocomposite Films Containing Functionalized Graphene Sheets[J]. ACS Appl Mater Interfaces,2010,2(12):3702-3708.
[5]	YANG Shiyong.Progress in High Temperature Polyimide Resin[J]. Polym Bull,2014,(12):23-28(in Chinese). 杨士勇. 耐高温聚酰亚胺树脂研究[J]. 高分子通报,2014,(12):23-28.
[6]	Pratt J R,Blackwell D A, Clair T L S,et al. 4,4'-Isophthaloyldiphthalic Anhydride Polyimides[J]. Polym Prepr,1988,29(1):128-129.
[7]	Pratt J R,Blackwell D A, St.clair T L,et al. 4,4'-Isophthaloyidiphthalic anhydride Polyimides[J]. Polym Eng Sci,1989,29(1):63-68.
[8]	Pratt J R,St.clair T L, Progar D J. Processable Polyimide Adhesive and Matrix Composite Resin:US, 4937317 A[P].1990-06-26.
[9]	SONG Cheng,SONG Caisheng. A Preparation Method of 4, 4'-Terephthaloyldiphthalic and Its Products and Uses:CN201310384452[P].2013-08-29(in Chinese). 宋琤,宋才生. 一种聚合级4, 4'-对苯二甲酰二邻苯二甲酸酐的制法及其产品和用途:CN201310384452[P].2013-08-29.
[10]	ZHAN Meidong,HONG Huiming,WANG Liyun,et al. Synthesis and Properties of Organosolubile Dikentone Anhydride Copolymides[J]. Polym Mater Sci Eng,2016,32(8):16-20(in Chinese). 詹美栋,洪慧铭,王利云,等. 一种可溶性双酮酐型共聚酰亚胺的合成及性能[J]. 高分子材料科学与工程,2016,32(8):16-20.
[11]	HU Shuncheng,CHEN Zhiqiang,HONG Huiming,et al. The Synthesis and Characterization of Novel Thermoplastic Polyimide Based on Diketone Anhydride[J]. J Jiangxi Norm Univ(Nat Sci),2016,40(4):415-419(in Chinese). 胡顺成,陈志强,洪慧铭,等. 新型热塑性的双酮酐型聚酰亚胺的合成与性能研究[J]. 江西师范大学学报(自然科学版),2016,40(4):415-419.
[12]	Seo Y,Lee S M,Kim D Y.Kinetic Study of the Imidization of a Poly(ester amic acid) by FT-Raman Spectroscopy[J]. Macromolecules,1997,30(13):3747-3753.
[13]	SONG Cheng,CHEN Zhiqiang,JIANG Yangcheng,et al. Synthesis and Properties of 4,4'-Terephthaloyldiphthalic/PMDA Anhydride Copolyimide[J]. Polym Mater Sci Eng,2015,12:27-31(in Chinese). 宋琤,陈志强,江杨诚,等. 4,4'-对苯二甲酰二邻苯二甲酸酐和均苯四甲酸酐共聚酰亚胺的合成与性能[J]. 高分子材料科学与工程,2015,31(12):27-31.
[14]	Vanherck K,Koeckelberghs G,Vankelecom I.Crosslinking Polyimides for Membrane Applications:A Review[J]. Prog Polym Sci,2013,38:874-896.
[15]	Liaw D J,Wang K L,Huang Y C,et al. Advanced Polyimide Materials:Syntheses, Physical Properties, and Applications[J]. Prog Polym Sci,2012,37:907-974

Synthesis and Properties of Super-high Temperature Diketone Anhydride Polyimides

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 6

Recommended Articles

Metrics

Comments

[1]	Yu-Fang SHI, Ying-Jin WANG, Jin-Yu SUN, Ming-Gen ZHAO. Synthesis, Characterization, Photothermal Properties of Dichalcone Containing Polymethoxy Aromatic Group [J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 235-240.
[2]	Cheng ZOU, Yan-Zi GAO, Mei-Na YU, Jiu-Mei XIAO, Lan-Ying ZHANG, Huai YANG. Recent Advances in Liquid Crystal/Polymer Composites and Their Applications in Reverse⁃mode Electrically Switchable Light⁃transmittance Controllable Films [J]. Chinese Journal of Applied Chemistry, 2021, 38(10): 1213-1225.
[3]	GAO Limin, LI Lu, ZHOU Guangyuan, WANG Honghua, ZHU Zhongli. Preparation and Properties of Siliceous Earth/ Phenolphthalein-Based Poly(arylene ether sulfone) Composites [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 524-530.
[4]	XU Hengzhi, WANG Huan, DAI Zhen, HUANG Yiping, XU Gewen*. Synthesis and Properties of Waterborne Polyurethane Based Tetramethyl Xylene Diisocyanate [J]. Chinese Journal of Applied Chemistry, 2012, 29(06): 623-627.
[5]	XU Hengzhi, WANG Huan, BAO Junjie, HUANG Yiping, XU Gewen*. Effect of the content of hard segment on the hydrogen bonding interactions and properties for waterborne polyurethanes [J]. Chinese Journal of Applied Chemistry, 2011, 28(07): 770-776.
[6]	HUANG Xueliang1,2, ZHU Fanghua2, YANG Junxiao1, ZHANG Lin2*. Synthesis and Properties of Diethyl Tetramethyl Disiloxane Bisbenzocyclobutene and Its Polymer [J]. Chinese Journal of Applied Chemistry, 2011, 28(06): 640-644.