A Tb3+ Coordination Polymer with Tetrazol Functional Sites:Construction and Fluorescent Sensing Property Toward Metal Ions

doi:10.11944/j.issn.1000-0518.2017.09.170188

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (9): 1046-1051.DOI: 10.11944/j.issn.1000-0518.2017.09.170188

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A Tb³⁺ Coordination Polymer with Tetrazol Functional Sites:Construction and Fluorescent Sensing Property Toward Metal Ions

LI Na^a,CHANG Ze^a^*,BU Xianhe^a^b

^aSchool of Materials Science and Engineering,National Institute for Advanced Materials,and Tianjin Key Laboratory of Metal and Molecule-Based Material Chemistry,Nankai University,Tianjin 300350,China
^bCollege of Chemistry,Nankai University,Tianjin 300071,China

Received:2017-06-01 Accepted:2017-07-05 Published:2017-08-31 Online:2017-08-31
Contact: CHANG Ze
Supported by:
Supported by the National Natural Science Foundation of China(No.15JCZDJC38800, No.16JCQNJC02400)

Abstract

Abstract:

Lanthanide coordination polymers have been widely investigated in fluorescent sensing owing to their characters in component, structure, and properties. However, the functional targeted construction of lanthanide coordination polymers is still a challenge. Herein, we report the construction, characterization, and properties investigation of a new Tb³⁺ coordination polymer, namely [Tb(TZI)(DMF)₂(H₂O)]·(H₂O)(1)(H₃TZI=5-(1H-tetrazol-5-yl)isophthalic acid and DMF=N,N-dimethylmethanamide). Utilizing the distinct affinities between Tb³⁺ ion and carboxylate/tetrazole groups, the construction of coordination polymer is well achieved, while the tetrazole group has been introduced into the framework of coordination polymer as sensing sites. As a result, complex 1 reveals ions dependent emissions enhancement owing to the coordination between the ions and the tetrazole sites, which could be utilized for the sensing of Zn²⁺ and Na⁺ ions. These results could be instructive for the fluorescent sensing function targeted construction of lanthanide coordination polymers.

Key words: coordination polymer, lanthanide metals, construction, fluorescent sensing

LI Na, CHANG Ze, BU Xianhe. A Tb³⁺ Coordination Polymer with Tetrazol Functional Sites:Construction and Fluorescent Sensing Property Toward Metal Ions[J]. Chinese Journal of Applied Chemistry, 2017, 34(9): 1046-1051.

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A Tb³⁺ Coordination Polymer with Tetrazol Functional Sites:Construction and Fluorescent Sensing Property Toward Metal Ions

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