Synthesis, Theoretical Investigation and Third-order Nonlinear Optical Properties of Novel Aromatic Chalcone Derivatives

doi:10.11944/j.issn.1000-0518.2016.10.160016

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (10): 1182-1188.DOI: 10.11944/j.issn.1000-0518.2016.10.160016

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Synthesis, Theoretical Investigation and Third-order Nonlinear Optical Properties of Novel Aromatic Chalcone Derivatives

SHI Yufang,SUN Jinyu,WANG Guilin,LIU Chengqi,ZHAO Minggen()

Key Laboratory of Materials and Computational Chemistry,Department of Chemistry,Xinzhou Normal University,Xinzhou 034000,Shanxi,China

Received:2016-01-11 Accepted:2016-05-30 Published:2016-10-08 Online:2016-10-08
Contact: ZHAO Minggen
Supported by:
Supported by the Key Discipline of Xinzhou Teachers University Subject(No.XK201205)

Abstract

Abstract:

Two novel of nonlinear optical(NLO) organic material, chalcone derivatives(1-(furan-2-yl)-3-(4-methoxyphenyl) acrylketone(1) and 1-(thiophen-2-yl)-3-(4-methoxyphenyl) acrylketone(2)), were synthesized and characterized by NMR, IR and HR-MS. The third-order nonlinear optical properties were measured by the 4f phase-coherent imaging system and the resulting relevant parameters were given as following with 4 nm pulse width and 440 nm laser wavelength:for compound 1:nonlinear absorption coefficient β=5.5×10^-10 m/W, nonlinear refractive coefficient n₂=-2.1×10^-17 m²/W, third-order nonlinear polarization χ⁽³⁾=1.58×10^-11 esu; for compound 2:β=-2.4×10^-10 m/W, n₂=0.3×10^-17 m²/W, χ⁽³⁾=0.50×10^-11 esu. The corresponding UV absorption and DSC curves were also investigated. Moreover, their orbital energy and polarization calculated by density functional theory demonstrate that electron transfer can be easily conducted intramolecularly caused by the easy polarizability of the targeted products. These materials show good potential application as the NLO materials.

Key words: chalcone derivatives, synthesis, 4f phase-coherent imaging system, third-order nonlinear optical properties

SHI Yufang, SUN Jinyu, WANG Guilin, LIU Chengqi, ZHAO Minggen. Synthesis, Theoretical Investigation and Third-order Nonlinear Optical Properties of Novel Aromatic Chalcone Derivatives[J]. Chinese Journal of Applied Chemistry, 2016, 33(10): 1182-1188.

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Synthesis, Theoretical Investigation and Third-order Nonlinear Optical Properties of Novel Aromatic Chalcone Derivatives

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