Synthesis and Nonlinear Optical Properties of 1-Ferrocenyl-3-((9-ethyl)carbazole-3-yl)acrylic Ketone

doi:10.11944/j.issn.1000-0518.2015.09.150020

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (9): 994-998.DOI: 10.11944/j.issn.1000-0518.2015.09.150020

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Synthesis and Nonlinear Optical Properties of 1-Ferrocenyl-3-((9-ethyl)carbazole-3-yl)acrylic Ketone

SHI Yufang,SUN Jinyu,LIU Chengqi,ZHAO Minggen()

Department of Chemistry,Xinzhou Teachers University,Xinzhou,Shanxi 034000,China

Received:2015-01-19 Accepted:2015-06-01 Published:2015-08-31 Online:2015-08-31
Contact: ZHAO Minggen
Supported by:
Supported by the Shanxi Province Education Department of Science and Technology Development Projects(No.20121022), the Key Discipline of Xinzhou Teachers University Subject(No.XK201205)

Abstract

Abstract:

A new nonlinear optical(NLO) organic material, 1-ferrocenyl-3-((9-ethyl) carbazole-3-yl) acrylic ketone(FCAK), was synthesized and characterized by IR, MS, NMR and element analysis. The title compound exhibits third-order nonlinear optical properties. The related parameters were obtained by powder technique using the Nd∶YAG laser. When the laser pulse is four nanoseconds, the nonlinear refractive index n₂ is -3.5×10^-18 m²/W, the nonlinear absorption coefficient β is -2.7×10^-11 m/W, the third-order nonlinear polarizability χ⁽³⁾ is 2.04×10^-12 esu, the third-order nonlinear molecular hyperpolarizability γ is 1.1×10^-30 esu. When the laser pulse is twenty one picoseconds, n₂ is 0.55×10^-18 m²/W, β is -0.6×10^-11 m/W, χ⁽³⁾ is 3.4×10^-13 esu, γ is 0.13×10^-30 esu.

Key words: ferrocenyl derivative, ferrocenyl-((ethyl)carbazole-yl)acrylic ketone, Chalcone, synthesis, nonlinear optical property

SHI Yufang,SUN Jinyu,LIU Chengqi,ZHAO Minggen. Synthesis and Nonlinear Optical Properties of 1-Ferrocenyl-3-((9-ethyl)carbazole-3-yl)acrylic Ketone[J]. Chinese Journal of Applied Chemistry, 2015, 32(9): 994-998.

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Synthesis and Nonlinear Optical Properties of 1-Ferrocenyl-3-((9-ethyl)carbazole-3-yl)acrylic Ketone

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