Preparation and Properties of Fluorine Containing CaO-P2O5-SiO2-Na2O-B2O3 Glass-ceramics

doi:10.11944/j.issn.1000-0518.2015.04.140235

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (4): 442-446.DOI: 10.11944/j.issn.1000-0518.2015.04.140235

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Preparation and Properties of Fluorine Containing CaO-P₂O₅-SiO₂-Na₂O-B₂O₃ Glass-ceramics

JIANG Limei^a, ZOU Xiangyu^a, WEI Qinlei^a, SONG Qiong^{a, c}, DENG Shuang^a, ZHANG Hongbo^{a, *}, SU Chunhui^{a, b}

^aSchool of Chemistry Environmental Engineering,Changchun University of Science and Technology,Changchun 130022,China
^bChangchun Normal University Faculty of Chemistry,Changchun,130032,China
^cJilin Teacher's Institute of Engineering and Technology,Changchun 130032,Chin

Received:2014-07-03 Published:2015-04-10 Online:2015-04-10
Contact: Corresponding author:ZHANG Hongbo, professor; Tel:0431-85583159; E-mail:zhb5388460@126.com; Research interests:photoelectric functional materials
Supported by:
Supported by the National “863” Project(No.2011AA030204), the Research Project of Science and Technology Department of Jilin Province(No.20120341)

Abstract

Abstract:

By partially substituting of CaO with CaF₂, in CaO-P₂O₅-SiO₂-Na₂O-B₂O₃ glass-ceramic system a new precursor powder was prepared by the sol-gel method. Its crystallization temperature was determined by TG-DSC at 865 ℃. The main crystal phase of the glass-ceramics is Na₆Ca₃Si₆O₁₈. The microstructures and properties of this glass-ceramics were characterized by X-ray diffractometry (XRD), Fourier transform infrared spectroscopy(FTIR), scanning electron microscopy(SEM) and in vitro assays. By addition of CaF₂, the volume density, bending strength and microhardness of the glass-ceramics are significantly improved, but the bioiogical activity of the glass-ceramics is maintained.

Key words: sol-gel method, CaF₂, glass-ceramics, biological activity

CLC Number:

O611.4

JIANG Limeia, ZOU Xiangyua, WEI Qinleia, SONG Qionga, c, DENG Shuanga, ZHANG Hongboa, , SU Chunhuia, b. Preparation and Properties of Fluorine Containing CaO-P₂O₅-SiO₂-Na₂O-B₂O₃ Glass-ceramics[J]. Chinese Journal of Applied Chemistry, 2015, 32(4): 442-446.

References

[1] Hench L L,Splinter R J,Allen W C, et al . Bonding Mechanisms at the Interface of Ceramic Prosthetic Materials[J]. Biomed Mater Res Symp ,1971,5(6):117-141.
[2] Cabal B,Malpartida F,Torrecillas R, et al . The Development of Bioactive Glass-ceramic Substrates with Biocide Activity[J]. A dv Eng Mater ,2011,13(16):B462-B466.
[3] Padmanabhann S K,Gervaso F,Carrozzo M, et al . Wollastonite/hydroxyapatite Scaffolds with Improved Mechanical, Bioactive and Biodegradable Properties for Bone Tissue Engineering[J]. Ceram Int ,2013,39(1):619-627.
[4] Hench L L. Genetic Design of Bioactive Glass[J]. Eur Ceram Soc ,2009,29(12):57-65.
[5] Hench L L. The story of bioglass[J]. Mater Sci Mater Med ,2006,17(11):967-978.
[6] CAI Shu,LI Jianxin,WANG Dongmei, et al . The Formation and Biological Activity in vitro of Apatite of CaO-P 2 O 5 - Na 2 O-B 2 O 3 Glass Ceramics Use Sol-gel Method[J]. Rare Met Mater Eng ,2011,40(Suppl1):40-43(in Chinese). 蔡舒,李建新,王冬梅,等. CaO-P 2 O 5 -Na 2 O-B 2 O 3 溶胶-凝胶玻璃陶瓷体外磷灰石的形成和生物活性[J]. 稀有金属材料与工程,2011,40(增刊1):40-43.
[7] Simon V,Lucacel R C,Titorencu I, et al . Physical Properties and Biological Performance of Bioactive Glasses and Glass-ceramics Tested in vitro [J]. Key Eng Mater ,2012,494(1):85-89.
[8] LU Zhi,LIU Yong. Influence of Phase Composition on the Mechanical Properties of the SiO 2 -Al 2 O 3 -MgO-CaO -F - Glass Veramics[J]. Mater Sci Eng Powder Metall ,2013,18(5):693-699(in Chinese). 逯峙,刘咏. 相组成对SiO 2 -Al 2 O 3 -MgO-CaO-F - 玻璃陶瓷力学性能的影响[J]. 粉末冶金材料科学与工程,2013,18(5):693-699.
[9] YANG Weizhong,ZHOU Dali,YIN Guangfu, et al . Research of Bioactive Glass Ceramic System Use Sol-gel Method[J]. J Chinese Ceram Soc ,2004,32(2):172-176(in Chinese). 杨为中,周大利,尹光福,等. 溶胶-凝胶法制备生物活性玻璃陶瓷的研究[J]. 硅酸盐学报,2004,32(2):172-176.
[10] Ma J,Chen C Z,Wang D G, et al . In vitro Degrada-bility and Bioactivity of Mesoporous CaO-MgO-P 2 O 5 -SiO 2 Glasses Synthesized by Sol-gel Method[J]. Sol-Gel Sci Technol ,2010,54(1):69-76.
[11] Kokubo T,Kushitani H,Sakka S, et al . Solutions Able to Reproduce in vivo Surface-structure Changes in Bioactive Glass-ceramic A-W[J]. Biomed Mater Res ,1990,24(6):721-734.
[12] Atiar R M,Bikram J B. Microstructure, Mechanical, and in vitro Properties of Mica Glass-ceramics with Varying Fluorine Content[J]. Mater Sci Mater Med ,2009,20(4):869-882.

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Preparation and Properties of Fluorine Containing CaO-P₂O₅-SiO₂-Na₂O-B₂O₃ Glass-ceramics

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