Application of Chitosan/Polyvinyl Alcohol Complex Film in Fabrics' Electroless Plating

doi:10.11944/j.issn.1000-0518.2015.02.140124

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (2): 200-206.DOI: 10.11944/j.issn.1000-0518.2015.02.140124

• Full Papers • Previous Articles Next Articles

Application of Chitosan/Polyvinyl Alcohol Complex Film in Fabrics' Electroless Plating

LIU Yan^a, YU Dan^{a, b}, LI Weiya^a, GAO Cuicui^a, WANG Wei^{a, b, *}

aCollege of Chemistry,Chemical Engineering and Biotechnology
bKey Laboratory of Science & Technology of Eco-Textile, Ministry of Education,Donghua University,Shanghai 201620,China

Received:2014-04-14 Revised:2014-05-14 Published:2015-02-10 Online:2015-02-10
Contact: Corresponding author:WANG Wei, professor; Tel:021-67792618; Fax:021-67792306; E-mail:wangv@dhu.edu.cn; Research interests:textile functional finishing
Supported by:
; Supported by the National Natural Science Foundation of China(No.51403032)

Abstract

Abstract:

Auto-catalyzed film on polyester(PET) surface was prepared through chitosan(CS)/polyvinyl alcohol(PVA) complex film with PdCl₂, which successfully initiated the nickel electroless plating afterwards. The CS/PVA complex film has interpenetrating networks(IPN) structure with strong hydrogen bonds in it. The chemical structure of complex film was characterized by Fourier transform infrared spectroscopic(FT-IR) analysis and tensile strength test. After electroless plating, the surface morphology, thermal stability, electromagnetic shielding effectiveness(SE) and adhesion strength of the metallized PET fabric were investigated by scanning electron microscopy(SEM), thermogravimetry(TG), SE test and washing fastness test. The results show that the nickel layer can be obtained on treated PET fabrics with good conductivity, fine uniformity and strong adhesion strength.

Key words: chitosan, polyvinyl alcohol, electromagnetic shielding, electroless plating, polyester

CLC Number:

O636.1

LIU Yan, YU Dan, LI Weiya, GAO Cuicui, WANG Wei. Application of Chitosan/Polyvinyl Alcohol Complex Film in Fabrics' Electroless Plating[J]. Chinese Journal of Applied Chemistry, 2015, 32(2): 200-206.

References

[1] RU Qiang,HU Shejun,HU Xianqi, et al . Electromagnetic Shielding Theory and the Preparation of Shielding Material[J]. Packaging Eng ,2004,(5):21-23,49(in Chinese). 汝强,胡社军,胡显奇,等. 电磁屏蔽理论及屏蔽材料的制备[J]. 包装工程,2004,(5):21-23,49.
[2] Schiffman J D,Schauer C L. One-Step Electrospinning of Cross-Linked Chitosan Fibers[J]. Biomacromolecules ,2007,8(9):2665-2667.
[3] Mojca Kerec,Marija Bogataj,Peter Verani c ˇ , et al . Permeability of Pig Urinary Bladder Eall:the Effect of Chitosan and the Role of Calcium[J]. Eur J Pharm Sci ,2005,25(1):113-121.
[4] Xu C X,Chen R Y,Zheng X, et al . Preparation of PVA-GA-CS/PVA-Fe-SA Bipolar Membrane and Its Application in Electro-generation of 2,2-Dimethyl-3-hydroxypropionic Acid[J]. J Membr Sci ,2008,307(2):218-224.
[5] Zhou Y S,Yang D Z, et al . Electrospun Water-Soluble Carboxyethyl Chitosan/Poly(vinyl alcohol) Nanofibrous Membrane as Potential Wound Dressing for Skin Regeneration[J]. Biomacromolecules ,2007,9(1):349-354.
[6] Dae-Joon Kim,II-Seok Park,Myung-Hyun Lee. Tensile Strength of Aqueous-based Alumina Tapes Using a PVP PVA Gelatin Cobinder[J]. Ceram Int ,2005,31(4):577-581.
[7] WANG Kangjian,DAN Weihua,CAO Rui, et al . Structural Characterization and Properties of Chitosan/PVA Blend Films[J]. Mater Rev ,2009,(10):102-105(in Chinese). 王康建,但卫华,曹睿,等. 壳聚糖/聚乙烯醇共混膜的结构表征及性能研究[J]. 材料导报,2009,(10):102-105.
[8] LI Qinhua,HUANG Lei,LI Hui, et al . Preparation of Chitosan/polyvinyl Alcohol Composite Scaffold at Different Mass Ratios:Comparison of Structure and Characteristics[J]. J Clin Rehab Tissue Eng Res ,2010,(3):477-481(in Chinese). 李沁华,黄雷,李辉,等. 不同质量配比壳聚糖/聚乙烯醇复合材料组织工程支架的制备:结构及性能比较[J]. 中国组织工程研究与临床康复,2010,(3):477-481.
[9] Ye Y C,Dan W H,Zeng R, et al . Miscibility Studies on the Blends of Collagen/Chitosan by Dilute Solution Viscometry[J]. Eur Polym J ,2007,43(5):2066-2071.
[10] YE Yichun,DAN Weihua,ZENG Rui, et al . Study on theMolecular Interactions Between Collagen and Chitosan[J]. Polym Mater Sci Eng ,2007,(5):112-115(in Chinese). 叶易春,但卫华,,等. 胶原与壳聚糖分子间的作用力[J]. 高分子材料科学与工程,2007,(5):112-115.
[11] ZHAO Yaping,CAI Zaisheng. Application of Electroless Plating in Textile Metallization[J]. Dye Finish ,2008,(12):39-42(in Chinese). 赵亚萍,蔡再生. 化学镀在织物金属化处理中的应用[J]. 印染,2008,(12):39-42.
[12] XU Wenlong,XIONG Jie,XU Qin, et al . Preparation and Properties of Silver Electroless Plated PET Fabrics[J]. J Text Res ,2011,(9):42-46,52(in Chinese). 徐文龙,熊杰,徐勤,等. 化学镀银涤纶织物的制备及其性能[J]. 纺织学报,2011,(9):42-46,52.
[13] WU Jianwen,WANG Wei,YU Dan, et al . Electromagnetic Shielding Cotton Fabric Prepared with Chemical Plating[J]. Dye Finish ,2010,(24):7-10,29(in Chinese). 吴建文,王炜,俞丹,等. 棉织物电磁屏蔽化学镀[J]. 印染,2010,(24):7-10,29.
[14] Chie Sawatari,Tetsuo Kondo. Interchain Hydrogen Bonds in Blend Films of Poly(vinyl alcohol) and Its Derivatives with Poly(ethylene oxide)[J]. Macromolecules ,1999,32(6):1949-1955.
[15] WU Jinguang. Technology and Application of Modern Fourier Transform Infrared Spectroscopy[M]. Beijing:Science Press,1996:580(in Chinese). 吴瑾光. 近代傅里叶变换红外光谱技术及应用[M]. 北京:科学技术出版社,1996:580.
[16] Pearson F G,Marchessault R H,Liang C Y. Infrared Spectra of Crystalline Polysaccharides.V.Chitin[J]. J Polym Sci ,1960,43(141):101-116.
[17] CUI Sheng,SHEN Xiaodong,YUAN Linsheng, et al . Research Development of Electromagnetic Interference Shielding and Wave-absorbing Materials[J]. Electron Compon Mater ,2005,(1):57-61(in Chinese). 崔升,沈晓东,袁林生,等. 电磁屏蔽和吸波材料的研究进展[J]. 电子元件与材料,2005,(1):57-61.
[18] ZHONG Linxin,ZHANG Meiyun,CHEN Junzhi, et al . Study on the Shielding Properties of Carbon Fiber Shielding Paper[J]. Trans China Pulp Paper ,2008,(4):90-93(in Chinese). 钟林新,张美云,陈均志,等. 碳纤维屏蔽纸屏蔽性能的研究[J]. 中国造纸学报,2008,(4):90-93.

Application of Chitosan/Polyvinyl Alcohol Complex Film in Fabrics' Electroless Plating

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Li-Juan YAN, Tian-He GAO, Dong-Jian SHI, Ming-Qing CHEN. Preparation and Properties of Eugenol/Modified Polyvinyl Alcohol Antibacterial Composite Films [J]. Chinese Journal of Applied Chemistry, 2023, 40(4): 527-535.
[2]	Yu-Zhu CHEN, Si-Si LIU, Meng-Meng ZHANG, Xiang-De LIN, Dong-Dong ZENG. Polyurethane Dressing Based on Antibacterial Chitosan/Carboxymethyl Cellulose Composite Drug Coating [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 252-260.
[3]	Xu-Juan HUANG, Ting WANG, Zheng-Qing DING, Xin-Xin YANG, Zhao-Sheng CAI, Shi-Bing SHANG. Preparation of Hydrogels Based on Dehydroabietyl Polyoxyethylene Glycidyl Ether Grafted Hydroxyethyl Chitosan and Their Properties [J]. Chinese Journal of Applied Chemistry, 2022, 39(9): 1421-1428.
[4]	Bing-Gang CHEN, San-Rong LIU, Zi-Jiang JIANG, Xi-Fei YU. Preparation and Properties Characterization of Hydrophilic Polysiloxane and Polyvinyl Alcohol Composite as Skin Barrier Material [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1224-1236.
[5]	ZHANG Qiao-Feng, LI Guo, JIANG Jin-Qiang, LIU Zhao-Tie. Preparation and Luminescent Properties of Linear Multi-hydroxy Polyester [J]. Chinese Journal of Applied Chemistry, 2021, 38(8): 938-945.
[6]	LIN Qiu-Peng, ZHANG Zhu-Ying, SHI Dong-Jian, PEI Ze-Jun, CHEN Ming-Qing, NI Zhong-Bin. Preparation and Properties of Sustained Release Chitosan/Chlorhexidine Acetate Composite Microspheres [J]. Chinese Journal of Applied Chemistry, 2021, 38(12): 1599-1611.
[7]	ZHAO Bingbing, DENG Dongyang, CHEN Guihua, SONG Qingmei, FU Jianping, ZHANG Sukun, ZHOU Chengyong, JÜ Yongming. Main Influencing Factors and Removal Mechanism of Phosphate Anions by Chitosan-Fe(III) Composite Gel Beads [J]. Chinese Journal of Applied Chemistry, 2020, 37(6): 673-682.
[8]	ZHANG Shouyan, HU Jianglei, SHI Xincui, ZHANG Peibiao, ITO Yoshihiro. Preparation of Electroactive and Bioactive DOPA-Jointed Insulin-Like Growth Factor-1@Poly(glycolide-lactide)/Poly(3-hexylthiophene) Electrospinning Fiber and Its Application in Neural Tissue Engineering [J]. Chinese Journal of Applied Chemistry, 2019, 36(9): 1003-1014.
[9]	BAO Jinping, FAN Sufang, YANG Guoyu, WANG Zhimin, WANG Ying, LIU Xiaohua, XU Cuilian. Synthesis and Antifungal Activities of Chitosan Oligosaccharide Thiosemicarbazone Schiff Base Cu(Ⅱ) Complex [J]. Chinese Journal of Applied Chemistry, 2019, 36(5): 500-508.
[10]	ZHANG Bin,Sun Xuejiao,Lü Chengwei,YU Shijun. Synthesis and Fluorescent Properties of Polyesters Containing 8-Hydroxyquinoline Side Groups and Their Zn(Ⅱ) and Al(Ⅲ) Complexes [J]. Chinese Journal of Applied Chemistry, 2019, 36(3): 306-313.
[11]	SUN Qi, WANG Liqiu, LIU Yang, GUO Chenxiao, WANG Pengjun, LIU Xuelong, ZHANG Xiaobo, ZHENG Lihui, LIU Liping. Preparation and Properties of Near Infrared Polyvinyl Alcohol Fluorescent Polymer Materials [J]. Chinese Journal of Applied Chemistry, 2018, 35(1): 53-59.
[12]	PENG Bingxian, ZHOU Aihong. Adsorptive Removal of Profenofos from Aqueous Solution by Chitosan/Pumice [J]. Chinese Journal of Applied Chemistry, 2017, 34(4): 464-471.
[13]	WU Yan, GUO Zhaonan, LYU Chengwei, YU Shijun. Synthesis and Properties of Polyesters Containing 8-Hydroxyquinoline Side Groups and Their Zn(Ⅱ), Al(Ⅲ) Complexes [J]. Chinese Journal of Applied Chemistry, 2017, 34(3): 338-344.
[14]	ZHANG Fan, WANG Lulu, WANG Jilin, FENG Ruijiang, ZHANG Yang. Gemini-type Cationic Molecules-Styrene Block Polymer Anion Conducting Membrane Prepared by in-situ Polymerization [J]. Chinese Journal of Applied Chemistry, 2016, 33(6): 693-700.
[15]	LU Yan, WU Siyu, MA Baiqing, SHI Jia, JIN Qifeng, YU Shijun. Synthesis and Properties of Polyesters Containing Schiff Base Side Groups and Their Zinc Complexes [J]. Chinese Journal of Applied Chemistry, 2016, 33(4): 452-458.